TY - JOUR
T1 - (4,7-dimethyl-1,10-phenanthroline)(ethylenediamine)platinum(II) dichloride tris(deuterium oxide) solvate
AU - Brodie, C. R.
AU - Turner, P.
AU - Wheate, N. J.
AU - Aldrich-Wright, J. R.
PY - 2006/11
Y1 - 2006/11
N2 - In the molecule of the title compound, [Pt(C14H12N2)(C2H4D4N2)]Cl2·3D2O, the complex dication has square-planar coordination to the PtII atom from N-donor atoms. A small tilt of 4.34 (6)° is observed between the plane of the phenanthroline (phen) ligand and the coordination plane. The phen ligands are assembled along [010], with π–π stacking interactions between phen ligands of interleaved complexes. The structure also reveals hydrogen-bond interactions between the complex ion, its counter-ions and the solvent molecules. The introduction of methyl residues onto the phen ligand at positions 4 and 7 does not appear to alter the geometry of the complex significantly.
AB - In the molecule of the title compound, [Pt(C14H12N2)(C2H4D4N2)]Cl2·3D2O, the complex dication has square-planar coordination to the PtII atom from N-donor atoms. A small tilt of 4.34 (6)° is observed between the plane of the phenanthroline (phen) ligand and the coordination plane. The phen ligands are assembled along [010], with π–π stacking interactions between phen ligands of interleaved complexes. The structure also reveals hydrogen-bond interactions between the complex ion, its counter-ions and the solvent molecules. The introduction of methyl residues onto the phen ligand at positions 4 and 7 does not appear to alter the geometry of the complex significantly.
UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=mq-pure-production&SrcAuth=WosAPI&KeyUT=WOS:000241691500148&DestLinkType=FullRecord&DestApp=WOS_CPL
U2 - 10.1107/S1600536806043376
DO - 10.1107/S1600536806043376
M3 - Article
SN - 2056-9890
VL - 62
SP - M3137-M3139
JO - Acta Crystallographica Section E: Crystallographic Communications
JF - Acta Crystallographica Section E: Crystallographic Communications
ER -