Abstract
Synthesis of a new 'capped' porphyrin 3 with rigid 1,2,3-triazole linkers between the porphyrin and 'capping' group has been achieved. A 'click' reaction, the copper(I)-catalysed variant of the Huisgen 1,3-dipolar cycloaddition, is used to create four linkages concomitantly under anhydrous conditions in N,N-dimethylformamide.
| Original language | English |
|---|---|
| Pages (from-to) | 2147-2149 |
| Number of pages | 3 |
| Journal | Synlett |
| Issue number | 14 |
| DOIs | |
| Publication status | Published - 22 Aug 2008 |
Keywords
- 1,2,3-triazoles
- 1,3-dipolar cycloaddition
- Alkyne
- Azide
- Porphyrin