A facile and novel route to unprecedented manganese C4 cumulenic complexes

Koushik Venkatesan; Francisco J. Fernández; Olivier Blacque; Thomas Fox; Montserrat Alfonso; Helmut W. Schmalle; Heinz Berke

A facile and novel route to unprecedented manganese C₄ cumulenic complexes

Koushik Venkatesan, Francisco J. Fernández, Olivier Blacque, Thomas Fox, Montserrat Alfonso, Helmut W. Schmalle, Heinz Berke^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The theoretically characterized (DFT) C₄ cumulenic species Mn(C₅H₄R)(dmpe) {=C=C=C=C(SnPh₃)₂} was obtained by photolysis of the C_sp2-Sn bond in the vinylidene complex Mn(C₅H₄R)(dmpe)[=C=C(SnPh ₃)-C≡CSnPh₃], which in turn was prepared by a thermal reaction from MnC₅H₄R(dmpe)(C₇H ₈) and Ph₃Sn-C₄-SnPh₃.

Original language	English
Pages (from-to)	2006-2008
Number of pages	3
Journal	Chemical Communications
Volume	9
Issue number	16
Publication status	Published - 21 Aug 2003
Externally published	Yes

Cite this

@article{9612a5728b1346249baa645214281104,

title = "A facile and novel route to unprecedented manganese C4 cumulenic complexes",

abstract = "The theoretically characterized (DFT) C4 cumulenic species Mn(C5H4R)(dmpe) {=C=C=C=C(SnPh3)2} was obtained by photolysis of the Csp2-Sn bond in the vinylidene complex Mn(C5H4R)(dmpe)[=C=C(SnPh 3)-C≡CSnPh3], which in turn was prepared by a thermal reaction from MnC5H4R(dmpe)(C7H 8) and Ph3Sn-C4-SnPh3.",

author = "Koushik Venkatesan and Fern{\'a}ndez, {Francisco J.} and Olivier Blacque and Thomas Fox and Montserrat Alfonso and Schmalle, {Helmut W.} and Heinz Berke",

year = "2003",

month = aug,

day = "21",

language = "English",

volume = "9",

pages = "2006--2008",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - A facile and novel route to unprecedented manganese C4 cumulenic complexes

AU - Venkatesan, Koushik

AU - Fernández, Francisco J.

AU - Blacque, Olivier

AU - Fox, Thomas

AU - Alfonso, Montserrat

AU - Schmalle, Helmut W.

AU - Berke, Heinz

PY - 2003/8/21

Y1 - 2003/8/21

N2 - The theoretically characterized (DFT) C4 cumulenic species Mn(C5H4R)(dmpe) {=C=C=C=C(SnPh3)2} was obtained by photolysis of the Csp2-Sn bond in the vinylidene complex Mn(C5H4R)(dmpe)[=C=C(SnPh 3)-C≡CSnPh3], which in turn was prepared by a thermal reaction from MnC5H4R(dmpe)(C7H 8) and Ph3Sn-C4-SnPh3.

AB - The theoretically characterized (DFT) C4 cumulenic species Mn(C5H4R)(dmpe) {=C=C=C=C(SnPh3)2} was obtained by photolysis of the Csp2-Sn bond in the vinylidene complex Mn(C5H4R)(dmpe)[=C=C(SnPh 3)-C≡CSnPh3], which in turn was prepared by a thermal reaction from MnC5H4R(dmpe)(C7H 8) and Ph3Sn-C4-SnPh3.

UR - http://www.scopus.com/inward/record.url?scp=0041565265&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0041565265

SN - 1359-7345

VL - 9

SP - 2006

EP - 2008

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

A facile and novel route to unprecedented manganese C₄ cumulenic complexes

Abstract

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