A Mössbauer study of the relaxation behavior of dilute Fe3+ in LiScO2 and mullite

B. L. Dickson; K. K P Srivastava

doi:10.1016/0022-4596(76)90158-4

A Mössbauer study of the relaxation behavior of dilute Fe³⁺ in LiScO₂ and mullite

B. L. Dickson^*, K. K P Srivastava

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Mössbauer spectra of dilute Fe³⁺ in LiScO₂ and mullite have been studied over the temperature range 4 to 295°K. The hyperfine spectrum of the doublet ± 1 2 in mullite has been identified up to room temperature along with the spectrum of the doublet ± 5 2, which indicates that the spin-lattice relaxation times of doublets ± 5 2 and ± 1 2 are very similar in this system. The high value of the E D ratio for tetrahedral Fe³⁺ in mullite has made possible the observation of well-resolved hyperfine spectra of the doublet ± 1 2 even in zero applied field.

Original language	English
Pages (from-to)	117-123
Number of pages	7
Journal	Journal of Solid State Chemistry
Volume	19
Issue number	2
DOIs	https://doi.org/10.1016/0022-4596(76)90158-4
Publication status	Published - 1976

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10.1016/0022-4596(76)90158-4

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title = "A M{\"o}ssbauer study of the relaxation behavior of dilute Fe3+ in LiScO2 and mullite",

abstract = "M{\"o}ssbauer spectra of dilute Fe3+ in LiScO2 and mullite have been studied over the temperature range 4 to 295°K. The hyperfine spectrum of the doublet ± 1 2 in mullite has been identified up to room temperature along with the spectrum of the doublet ± 5 2, which indicates that the spin-lattice relaxation times of doublets ± 5 2 and ± 1 2 are very similar in this system. The high value of the E D ratio for tetrahedral Fe3+ in mullite has made possible the observation of well-resolved hyperfine spectra of the doublet ± 1 2 even in zero applied field.",

author = "Dickson, {B. L.} and Srivastava, {K. K P}",

year = "1976",

doi = "10.1016/0022-4596(76)90158-4",

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pages = "117--123",

journal = "Journal of Solid State Chemistry",

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T1 - A Mössbauer study of the relaxation behavior of dilute Fe3+ in LiScO2 and mullite

AU - Dickson, B. L.

AU - Srivastava, K. K P

PY - 1976

Y1 - 1976

N2 - Mössbauer spectra of dilute Fe3+ in LiScO2 and mullite have been studied over the temperature range 4 to 295°K. The hyperfine spectrum of the doublet ± 1 2 in mullite has been identified up to room temperature along with the spectrum of the doublet ± 5 2, which indicates that the spin-lattice relaxation times of doublets ± 5 2 and ± 1 2 are very similar in this system. The high value of the E D ratio for tetrahedral Fe3+ in mullite has made possible the observation of well-resolved hyperfine spectra of the doublet ± 1 2 even in zero applied field.

AB - Mössbauer spectra of dilute Fe3+ in LiScO2 and mullite have been studied over the temperature range 4 to 295°K. The hyperfine spectrum of the doublet ± 1 2 in mullite has been identified up to room temperature along with the spectrum of the doublet ± 5 2, which indicates that the spin-lattice relaxation times of doublets ± 5 2 and ± 1 2 are very similar in this system. The high value of the E D ratio for tetrahedral Fe3+ in mullite has made possible the observation of well-resolved hyperfine spectra of the doublet ± 1 2 even in zero applied field.

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DO - 10.1016/0022-4596(76)90158-4

M3 - Article

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JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

IS - 2

ER -

A Mössbauer study of the relaxation behavior of dilute Fe³⁺ in LiScO₂ and mullite

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