A novel reduction of polycarboxylic acids into their corresponding alkanes using n-butylsilane or diethylsilane as the reducing agent

Rama D. Nimmagadda; Christopher McRae

doi:10.1016/j.tetlet.2006.03.111

A novel reduction of polycarboxylic acids into their corresponding alkanes using n-butylsilane or diethylsilane as the reducing agent

Rama D. Nimmagadda, Christopher McRae^*

^*Corresponding author for this work

Faculty of Science and Engineering

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

A convenient one-pot reaction has been developed for the reduction of polycarboxylic acids on aliphatic and aromatic systems to their corresponding alkanes. The reduction utilises either diethylsilane or n-butylsilane as the reducing agent in the presence of the Lewis acid catalyst tris(pentafluorophenyl)borane.

Original language	English
Pages (from-to)	3505-3508
Number of pages	4
Journal	Tetrahedron Letters
Volume	47
Issue number	21
DOIs	https://doi.org/10.1016/j.tetlet.2006.03.111
Publication status	Published - 22 May 2006

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10.1016/j.tetlet.2006.03.111

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title = "A novel reduction of polycarboxylic acids into their corresponding alkanes using n-butylsilane or diethylsilane as the reducing agent",

abstract = "A convenient one-pot reaction has been developed for the reduction of polycarboxylic acids on aliphatic and aromatic systems to their corresponding alkanes. The reduction utilises either diethylsilane or n-butylsilane as the reducing agent in the presence of the Lewis acid catalyst tris(pentafluorophenyl)borane.",

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AU - Nimmagadda, Rama D.

AU - McRae, Christopher

PY - 2006/5/22

Y1 - 2006/5/22

N2 - A convenient one-pot reaction has been developed for the reduction of polycarboxylic acids on aliphatic and aromatic systems to their corresponding alkanes. The reduction utilises either diethylsilane or n-butylsilane as the reducing agent in the presence of the Lewis acid catalyst tris(pentafluorophenyl)borane.

AB - A convenient one-pot reaction has been developed for the reduction of polycarboxylic acids on aliphatic and aromatic systems to their corresponding alkanes. The reduction utilises either diethylsilane or n-butylsilane as the reducing agent in the presence of the Lewis acid catalyst tris(pentafluorophenyl)borane.

UR - https://www.scopus.com/pages/publications/33646036372

U2 - 10.1016/j.tetlet.2006.03.111

DO - 10.1016/j.tetlet.2006.03.111

M3 - Article

AN - SCOPUS:33646036372

SN - 0040-4039

VL - 47

SP - 3505

EP - 3508

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 21

ER -

A novel reduction of polycarboxylic acids into their corresponding alkanes using n-butylsilane or diethylsilane as the reducing agent

Abstract

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