A unified view of inorganic stereochemistry and stereochemical changes

Brian F G Johnson; Alison Rodger; Susan M. Colwell

doi:10.1016/0020-1693(94)03841-4

A unified view of inorganic stereochemistry and stereochemical changes

Brian F G Johnson^*, Alison Rodger, Susan M. Colwell

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Relationships between geometries adopted by compounds, ML_n, with different coordination numbers are developed and stereochemical changes in coordination compounds are analysed in terms of these relationships. The atom-atom interaction model (AAIM) view of molecular geometry in covalent species ML_n is used to quantify the discussion where required. The AAIM emphasises the importance of both ML bond and LL interaction energies.

Original language	English
Pages (from-to)	187-192
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	219
Issue number	1-2
DOIs	https://doi.org/10.1016/0020-1693(94)03841-4
Publication status	Published - 1994
Externally published	Yes

Keywords

Atom-atom interaction model
Coordination compounds
Stereochemistry

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10.1016/0020-1693(94)03841-4

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title = "A unified view of inorganic stereochemistry and stereochemical changes",

abstract = "Relationships between geometries adopted by compounds, MLn, with different coordination numbers are developed and stereochemical changes in coordination compounds are analysed in terms of these relationships. The atom-atom interaction model (AAIM) view of molecular geometry in covalent species MLn is used to quantify the discussion where required. The AAIM emphasises the importance of both ML bond and LL interaction energies.",

keywords = "Atom-atom interaction model, Coordination compounds, Stereochemistry",

author = "Johnson, {Brian F G} and Alison Rodger and Colwell, {Susan M.}",

year = "1994",

doi = "10.1016/0020-1693(94)03841-4",

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AU - Johnson, Brian F G

AU - Rodger, Alison

AU - Colwell, Susan M.

PY - 1994

Y1 - 1994

N2 - Relationships between geometries adopted by compounds, MLn, with different coordination numbers are developed and stereochemical changes in coordination compounds are analysed in terms of these relationships. The atom-atom interaction model (AAIM) view of molecular geometry in covalent species MLn is used to quantify the discussion where required. The AAIM emphasises the importance of both ML bond and LL interaction energies.

AB - Relationships between geometries adopted by compounds, MLn, with different coordination numbers are developed and stereochemical changes in coordination compounds are analysed in terms of these relationships. The atom-atom interaction model (AAIM) view of molecular geometry in covalent species MLn is used to quantify the discussion where required. The AAIM emphasises the importance of both ML bond and LL interaction energies.

KW - Atom-atom interaction model

KW - Coordination compounds

KW - Stereochemistry

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U2 - 10.1016/0020-1693(94)03841-4

DO - 10.1016/0020-1693(94)03841-4

M3 - Article

AN - SCOPUS:43949150344

SN - 0020-1693

VL - 219

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EP - 192

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1-2

ER -

A unified view of inorganic stereochemistry and stereochemical changes

Abstract

Keywords

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