Action of lewis acids on benzoylacetanilides and related compounds

B. Schiffman; B. Staskun

Action of lewis acids on benzoylacetanilides and related compounds

B. Schiffman, B. Staskun

Research output: Contribution to journal › Article › peer-review

Abstract

Benzoylacetanilides from 2-phenyl-4(1H)-quinolones when acted on by an equimolar proportion of AlCl₃, AlBr₃ or SnCl₄, BF₃ affords the difluoroborane derivative of the anilide. Complexes of the anilides with AlBr₃ and SnCl₄ were prepared and heated to give the 4(1H)-quinolones. A mechanism for the anilide-quinolone transformation is suggested.

Original language	English
Pages (from-to)	115-125
Number of pages	11
Journal	Tetrahedron
Volume	22
Issue number	SUPPL. 7
Publication status	Published - 1966

Cite this

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title = "Action of lewis acids on benzoylacetanilides and related compounds",

abstract = "Benzoylacetanilides from 2-phenyl-4(1H)-quinolones when acted on by an equimolar proportion of AlCl3, AlBr3 or SnCl4, BF3 affords the difluoroborane derivative of the anilide. Complexes of the anilides with AlBr3 and SnCl4 were prepared and heated to give the 4(1H)-quinolones. A mechanism for the anilide-quinolone transformation is suggested.",

author = "B. Schiffman and B. Staskun",

year = "1966",

language = "English",

volume = "22",

pages = "115--125",

journal = "Tetrahedron",

issn = "0040-4020",

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number = "SUPPL. 7",

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T1 - Action of lewis acids on benzoylacetanilides and related compounds

AU - Schiffman, B.

AU - Staskun, B.

PY - 1966

Y1 - 1966

N2 - Benzoylacetanilides from 2-phenyl-4(1H)-quinolones when acted on by an equimolar proportion of AlCl3, AlBr3 or SnCl4, BF3 affords the difluoroborane derivative of the anilide. Complexes of the anilides with AlBr3 and SnCl4 were prepared and heated to give the 4(1H)-quinolones. A mechanism for the anilide-quinolone transformation is suggested.

AB - Benzoylacetanilides from 2-phenyl-4(1H)-quinolones when acted on by an equimolar proportion of AlCl3, AlBr3 or SnCl4, BF3 affords the difluoroborane derivative of the anilide. Complexes of the anilides with AlBr3 and SnCl4 were prepared and heated to give the 4(1H)-quinolones. A mechanism for the anilide-quinolone transformation is suggested.

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M3 - Article

AN - SCOPUS:49949141321

SN - 0040-4020

VL - 22

SP - 115

EP - 125

JO - Tetrahedron

JF - Tetrahedron

IS - SUPPL. 7

ER -

Action of lewis acids on benzoylacetanilides and related compounds

Abstract

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