Active template synthesis of rotaxanes and molecular shuttles with switchable dynamics by four-component PdII-promoted Michael additions

Stephen M. Goldup; David A. Leigh; Paul J. Lusby; Roy T. McBurney; Alexandra M Z Slawin

doi:10.1002/anie.200705859

Active template synthesis of rotaxanes and molecular shuttles with switchable dynamics by four-component PdII-promoted Michael additions

Stephen M. Goldup, David A. Leigh, Paul J. Lusby, Roy T. McBurney, Alexandra M Z Slawin

Research output: Contribution to journal › Article › peer-review

61 Citations (Scopus)

Abstract

(Chemical Equation). Taking the Michael: Rotaxanes (see structure) and molecular shuttles are prepared in up to 99% yield by successive Pd ^II-promoted 1,4-conjugate additions in a one-pot four-component assembly process. This process represents the first active template reaction in which the template motif is retained in the interlocked product.

Original language	English
Pages (from-to)	3381-3384
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	18
DOIs	https://doi.org/10.1002/anie.200705859
Publication status	Published - 21 Apr 2008
Externally published	Yes

Keywords

Lewis acid catalysts
Molecular shuttles
Palladium
Rotaxanes
Template synthesis

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10.1002/anie.200705859

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abstract = "(Chemical Equation). Taking the Michael: Rotaxanes (see structure) and molecular shuttles are prepared in up to 99% yield by successive Pd II-promoted 1,4-conjugate additions in a one-pot four-component assembly process. This process represents the first active template reaction in which the template motif is retained in the interlocked product.",

keywords = "Lewis acid catalysts, Molecular shuttles, Palladium, Rotaxanes, Template synthesis",

author = "Goldup, {Stephen M.} and Leigh, {David A.} and Lusby, {Paul J.} and McBurney, {Roy T.} and Slawin, {Alexandra M Z}",

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AU - Lusby, Paul J.

AU - McBurney, Roy T.

AU - Slawin, Alexandra M Z

PY - 2008/4/21

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KW - Lewis acid catalysts

KW - Molecular shuttles

KW - Palladium

KW - Rotaxanes

KW - Template synthesis

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Active template synthesis of rotaxanes and molecular shuttles with switchable dynamics by four-component PdII-promoted Michael additions

Abstract

Keywords

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