Activity-composition relationships for pyrope-grossular garnet

B. J. Hensen*, R. Schmid, B. J. Wood

*Corresponding author for this work

    Research output: Contribution to journalArticle

    40 Citations (Scopus)

    Abstract

    Activity coefficients (γ) for grossular in pyrope-grossular garnet have been determined experimentally using the divariant assemblage garnet-anorthite-sillimanite (kyanite)-quartz. Values of γ for garnets with 10-12 mole % grossular have been obtained at 1000 °, 1100 °, 1200 ° and 1300 ° C at pressures between 15 and 21 Kb. The data are consistent with a symmetrical regular solid model for grossular-pyrope solid solutions. The interaction parameter (W) increases linearly with decreasing temperature and is given by W = 7460-4.3 T cals (T in °K). A solvus in the pyrope-grossular solid solution is predicted with a temperature of critical mixing of 629°C±90 ° C.

    Original languageEnglish
    Pages (from-to)161-166
    Number of pages6
    JournalContributions to Mineralogy and Petrology
    Volume51
    Issue number3
    DOIs
    Publication statusPublished - Sep 1975

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