Algal-derived polycyclic aromatic hydrocarbons in Paleogene lacustrine sediments from the Dongying Depression, Bohai Bay Basin, China

Huiyuan Xu, Simon C. George, Dujie Hou

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The sources and origins of polycyclic aromatic hydrocarbons (PAHs) in thirty eight Paleogene organic-rich shales and mudstones from the Shahejie Formation in the Dongying Depression, Bohai Bay Basin have been assessed. Phenanthrene, retene, cadalene, fluoranthene, pyrene, benz[a]anthracene, triphenylene, chrysene, benzofluoranthenes, benzo[e]pyrene, benzo[a]pyrene, indeno[1,2,3-cd]pyrene, benzo[ghi]perylene and coronene were identified in the sediments. The symmetrical 4-ring triphenylene was unequivocally identified by comparison with mass spectra and a synthetic standard. Key PAH ratios including fluoranthene/(fluoranthene + pyrene), benzo[a]anthracene/(benz[a]anthracene + chrysene), indeno[1,2,3-cd]pyrene/(indeno[1,2,3-cd]pyrene + benzo[ghi]perylene) and benzofluoranthene/(benzofluoranthene + benzo[e]pyrene) indicate a mainly diagenetic/catagenetic origin for the PAHs. The relative low abundance of the 6-ring indeno[1,2,3-cd]pyrene and benzo[ghi]perylene and the 7-ring coronene suggest the absence of larger, high temperature wildfires, either due to inadequate seasonality of the humid-arid climate, or limited terrigenous organic matter input. Phenanthrene and alkylphenanthrenes are likely derived from phytoplankton, based on the correlation of the relative abundance of C27 regular steranes and 1-methylphenanthrene and 9-methylphenanthrene. The methylphenanthrenes, triphenylene, alkyltriphenylenes and benzo[e]pyrene may share a common source as their occurrences are closely correlated. Four groups of samples were differentiated on the basis of the relative abundance and distribution patterns of benz[a]anthracene, triphenylene and chrysene, showing that these compounds are useful PAH markers in petroleum geochemistry. Thermal maturation effects are the major control on the relative abundance and distribution of the non-combustion derived PAHs (e.g. biphenyl, fluorene, fluoranthene, pyrene, benz[a]anthracene, triphenylene) in lacustrine sediments. Benz[a]anthracene decreases in relative abundance while triphenylene increases in relative abundance with burial depth. Correlation of the newly defined triphenylene-chrysene ratio (TCR; triphenylene/(triphenylene + chrysene) with burial depth and biomarker maturity parameters was observed, suggesting that it may be a useful maturity indicator for lacustrine oils and sediments in the Dongying Depression.

LanguageEnglish
Pages402-425
Number of pages24
JournalMarine and Petroleum Geology
Volume102
DOIs
Publication statusPublished - Apr 2019

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polycyclic aromatic hydrocarbons
pyrenes
pyrene
Paleogene
lacustrine deposit
China
PAH
sediments
anthracene
basin
relative abundance
fluoranthene
phenanthrene
rings
phytoplankton
shales
distribution (property)
biomarkers
geochemistry
crude oil

Cite this

@article{845f6417f1464956963a6b61a1baa2b5,
title = "Algal-derived polycyclic aromatic hydrocarbons in Paleogene lacustrine sediments from the Dongying Depression, Bohai Bay Basin, China",
abstract = "The sources and origins of polycyclic aromatic hydrocarbons (PAHs) in thirty eight Paleogene organic-rich shales and mudstones from the Shahejie Formation in the Dongying Depression, Bohai Bay Basin have been assessed. Phenanthrene, retene, cadalene, fluoranthene, pyrene, benz[a]anthracene, triphenylene, chrysene, benzofluoranthenes, benzo[e]pyrene, benzo[a]pyrene, indeno[1,2,3-cd]pyrene, benzo[ghi]perylene and coronene were identified in the sediments. The symmetrical 4-ring triphenylene was unequivocally identified by comparison with mass spectra and a synthetic standard. Key PAH ratios including fluoranthene/(fluoranthene + pyrene), benzo[a]anthracene/(benz[a]anthracene + chrysene), indeno[1,2,3-cd]pyrene/(indeno[1,2,3-cd]pyrene + benzo[ghi]perylene) and benzofluoranthene/(benzofluoranthene + benzo[e]pyrene) indicate a mainly diagenetic/catagenetic origin for the PAHs. The relative low abundance of the 6-ring indeno[1,2,3-cd]pyrene and benzo[ghi]perylene and the 7-ring coronene suggest the absence of larger, high temperature wildfires, either due to inadequate seasonality of the humid-arid climate, or limited terrigenous organic matter input. Phenanthrene and alkylphenanthrenes are likely derived from phytoplankton, based on the correlation of the relative abundance of C27 regular steranes and 1-methylphenanthrene and 9-methylphenanthrene. The methylphenanthrenes, triphenylene, alkyltriphenylenes and benzo[e]pyrene may share a common source as their occurrences are closely correlated. Four groups of samples were differentiated on the basis of the relative abundance and distribution patterns of benz[a]anthracene, triphenylene and chrysene, showing that these compounds are useful PAH markers in petroleum geochemistry. Thermal maturation effects are the major control on the relative abundance and distribution of the non-combustion derived PAHs (e.g. biphenyl, fluorene, fluoranthene, pyrene, benz[a]anthracene, triphenylene) in lacustrine sediments. Benz[a]anthracene decreases in relative abundance while triphenylene increases in relative abundance with burial depth. Correlation of the newly defined triphenylene-chrysene ratio (TCR; triphenylene/(triphenylene + chrysene) with burial depth and biomarker maturity parameters was observed, suggesting that it may be a useful maturity indicator for lacustrine oils and sediments in the Dongying Depression.",
keywords = "PAH, Aromatic hydrocarbon, Lacustrine, Shale, Dongying Depression, Bohai Bay Basin",
author = "Huiyuan Xu and George, {Simon C.} and Dujie Hou",
year = "2019",
month = "4",
doi = "10.1016/j.marpetgeo.2019.01.004",
language = "English",
volume = "102",
pages = "402--425",
journal = "Marine and Petroleum Geology",
issn = "0264-8172",
publisher = "Elsevier",

}

Algal-derived polycyclic aromatic hydrocarbons in Paleogene lacustrine sediments from the Dongying Depression, Bohai Bay Basin, China. / Xu, Huiyuan; George, Simon C.; Hou, Dujie.

In: Marine and Petroleum Geology, Vol. 102, 04.2019, p. 402-425.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Algal-derived polycyclic aromatic hydrocarbons in Paleogene lacustrine sediments from the Dongying Depression, Bohai Bay Basin, China

AU - Xu,Huiyuan

AU - George,Simon C.

AU - Hou,Dujie

PY - 2019/4

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N2 - The sources and origins of polycyclic aromatic hydrocarbons (PAHs) in thirty eight Paleogene organic-rich shales and mudstones from the Shahejie Formation in the Dongying Depression, Bohai Bay Basin have been assessed. Phenanthrene, retene, cadalene, fluoranthene, pyrene, benz[a]anthracene, triphenylene, chrysene, benzofluoranthenes, benzo[e]pyrene, benzo[a]pyrene, indeno[1,2,3-cd]pyrene, benzo[ghi]perylene and coronene were identified in the sediments. The symmetrical 4-ring triphenylene was unequivocally identified by comparison with mass spectra and a synthetic standard. Key PAH ratios including fluoranthene/(fluoranthene + pyrene), benzo[a]anthracene/(benz[a]anthracene + chrysene), indeno[1,2,3-cd]pyrene/(indeno[1,2,3-cd]pyrene + benzo[ghi]perylene) and benzofluoranthene/(benzofluoranthene + benzo[e]pyrene) indicate a mainly diagenetic/catagenetic origin for the PAHs. The relative low abundance of the 6-ring indeno[1,2,3-cd]pyrene and benzo[ghi]perylene and the 7-ring coronene suggest the absence of larger, high temperature wildfires, either due to inadequate seasonality of the humid-arid climate, or limited terrigenous organic matter input. Phenanthrene and alkylphenanthrenes are likely derived from phytoplankton, based on the correlation of the relative abundance of C27 regular steranes and 1-methylphenanthrene and 9-methylphenanthrene. The methylphenanthrenes, triphenylene, alkyltriphenylenes and benzo[e]pyrene may share a common source as their occurrences are closely correlated. Four groups of samples were differentiated on the basis of the relative abundance and distribution patterns of benz[a]anthracene, triphenylene and chrysene, showing that these compounds are useful PAH markers in petroleum geochemistry. Thermal maturation effects are the major control on the relative abundance and distribution of the non-combustion derived PAHs (e.g. biphenyl, fluorene, fluoranthene, pyrene, benz[a]anthracene, triphenylene) in lacustrine sediments. Benz[a]anthracene decreases in relative abundance while triphenylene increases in relative abundance with burial depth. Correlation of the newly defined triphenylene-chrysene ratio (TCR; triphenylene/(triphenylene + chrysene) with burial depth and biomarker maturity parameters was observed, suggesting that it may be a useful maturity indicator for lacustrine oils and sediments in the Dongying Depression.

AB - The sources and origins of polycyclic aromatic hydrocarbons (PAHs) in thirty eight Paleogene organic-rich shales and mudstones from the Shahejie Formation in the Dongying Depression, Bohai Bay Basin have been assessed. Phenanthrene, retene, cadalene, fluoranthene, pyrene, benz[a]anthracene, triphenylene, chrysene, benzofluoranthenes, benzo[e]pyrene, benzo[a]pyrene, indeno[1,2,3-cd]pyrene, benzo[ghi]perylene and coronene were identified in the sediments. The symmetrical 4-ring triphenylene was unequivocally identified by comparison with mass spectra and a synthetic standard. Key PAH ratios including fluoranthene/(fluoranthene + pyrene), benzo[a]anthracene/(benz[a]anthracene + chrysene), indeno[1,2,3-cd]pyrene/(indeno[1,2,3-cd]pyrene + benzo[ghi]perylene) and benzofluoranthene/(benzofluoranthene + benzo[e]pyrene) indicate a mainly diagenetic/catagenetic origin for the PAHs. The relative low abundance of the 6-ring indeno[1,2,3-cd]pyrene and benzo[ghi]perylene and the 7-ring coronene suggest the absence of larger, high temperature wildfires, either due to inadequate seasonality of the humid-arid climate, or limited terrigenous organic matter input. Phenanthrene and alkylphenanthrenes are likely derived from phytoplankton, based on the correlation of the relative abundance of C27 regular steranes and 1-methylphenanthrene and 9-methylphenanthrene. The methylphenanthrenes, triphenylene, alkyltriphenylenes and benzo[e]pyrene may share a common source as their occurrences are closely correlated. Four groups of samples were differentiated on the basis of the relative abundance and distribution patterns of benz[a]anthracene, triphenylene and chrysene, showing that these compounds are useful PAH markers in petroleum geochemistry. Thermal maturation effects are the major control on the relative abundance and distribution of the non-combustion derived PAHs (e.g. biphenyl, fluorene, fluoranthene, pyrene, benz[a]anthracene, triphenylene) in lacustrine sediments. Benz[a]anthracene decreases in relative abundance while triphenylene increases in relative abundance with burial depth. Correlation of the newly defined triphenylene-chrysene ratio (TCR; triphenylene/(triphenylene + chrysene) with burial depth and biomarker maturity parameters was observed, suggesting that it may be a useful maturity indicator for lacustrine oils and sediments in the Dongying Depression.

KW - PAH

KW - Aromatic hydrocarbon

KW - Lacustrine

KW - Shale

KW - Dongying Depression

KW - Bohai Bay Basin

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U2 - 10.1016/j.marpetgeo.2019.01.004

DO - 10.1016/j.marpetgeo.2019.01.004

M3 - Article

VL - 102

SP - 402

EP - 425

JO - Marine and Petroleum Geology

T2 - Marine and Petroleum Geology

JF - Marine and Petroleum Geology

SN - 0264-8172

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