Alkyl hydrogen sulphates. Part I. Hydrolysis in moist dioxan solution

B. D. Batts

doi:10.1039/J29660000547

Alkyl hydrogen sulphates. Part I. Hydrolysis in moist dioxan solution

B. D. Batts^*

^*Corresponding author for this work

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18 Citations (Scopus)

Abstract

The rate of hydrolysis of methyl and ethyl hydrogen sulphates increases by a factor of 10⁷ when the solvent is changed from pure water to moist dioxan. The reaction is acid-catalysed and the reaction species probably is the zwitterion R-O⁺H-SO₂-O^-. The effective strength of sulphuric acid in 98% dioxan-2% water was studied with the indicator p-nitroaniline.

Original language	English
Pages (from-to)	547-551
Number of pages	5
Journal	Dalton Transactions
DOIs	https://doi.org/10.1039/J29660000547
Publication status	Published - 1966
Externally published	Yes

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title = "Alkyl hydrogen sulphates. Part I. Hydrolysis in moist dioxan solution",

abstract = "The rate of hydrolysis of methyl and ethyl hydrogen sulphates increases by a factor of 107 when the solvent is changed from pure water to moist dioxan. The reaction is acid-catalysed and the reaction species probably is the zwitterion R-O+H-SO2-O-. The effective strength of sulphuric acid in 98% dioxan-2% water was studied with the indicator p-nitroaniline.",

author = "Batts, {B. D.}",

year = "1966",

doi = "10.1039/J29660000547",

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T1 - Alkyl hydrogen sulphates. Part I. Hydrolysis in moist dioxan solution

AU - Batts, B. D.

PY - 1966

Y1 - 1966

N2 - The rate of hydrolysis of methyl and ethyl hydrogen sulphates increases by a factor of 107 when the solvent is changed from pure water to moist dioxan. The reaction is acid-catalysed and the reaction species probably is the zwitterion R-O+H-SO2-O-. The effective strength of sulphuric acid in 98% dioxan-2% water was studied with the indicator p-nitroaniline.

AB - The rate of hydrolysis of methyl and ethyl hydrogen sulphates increases by a factor of 107 when the solvent is changed from pure water to moist dioxan. The reaction is acid-catalysed and the reaction species probably is the zwitterion R-O+H-SO2-O-. The effective strength of sulphuric acid in 98% dioxan-2% water was studied with the indicator p-nitroaniline.

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U2 - 10.1039/J29660000547

DO - 10.1039/J29660000547

M3 - Article

AN - SCOPUS:28944450575

SN - 1477-9226

SP - 547

EP - 551

JO - Dalton Transactions

JF - Dalton Transactions

ER -

Alkyl hydrogen sulphates. Part I. Hydrolysis in moist dioxan solution

Abstract

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