TY - JOUR
T1 - Alkyl hydrogen sulphates. Part II. The hydrolysis in aqueous acid solution
AU - Batts, B. D.
PY - 1966
Y1 - 1966
N2 - Oxygen-18 tracer studies were carried out on the hydrolysis of sodium methyl, ethyl, and isopropyl sulphates in aqueous perchloric acid and sodium hydroxide solutions. The reaction proceeds by sulphur-oxygen bond fission in acid solution and carbon-oxygen bond fission in alkaline solution. An A-1 mechanism is proposed for the hydrolysis reaction in aqueous acid solution.
AB - Oxygen-18 tracer studies were carried out on the hydrolysis of sodium methyl, ethyl, and isopropyl sulphates in aqueous perchloric acid and sodium hydroxide solutions. The reaction proceeds by sulphur-oxygen bond fission in acid solution and carbon-oxygen bond fission in alkaline solution. An A-1 mechanism is proposed for the hydrolysis reaction in aqueous acid solution.
UR - http://www.scopus.com/inward/record.url?scp=11144304893&partnerID=8YFLogxK
U2 - 10.1039/J29660000551
DO - 10.1039/J29660000551
M3 - Article
SP - 551
EP - 555
JO - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
JF - Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry
SN - 0022-4944
ER -