Alkyl hydrogen sulphates. Part II. The hydrolysis in aqueous acid solution

B. D. Batts

doi:10.1039/J29660000551

Alkyl hydrogen sulphates. Part II. The hydrolysis in aqueous acid solution

B. D. Batts^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Oxygen-18 tracer studies were carried out on the hydrolysis of sodium methyl, ethyl, and isopropyl sulphates in aqueous perchloric acid and sodium hydroxide solutions. The reaction proceeds by sulphur-oxygen bond fission in acid solution and carbon-oxygen bond fission in alkaline solution. An A-1 mechanism is proposed for the hydrolysis reaction in aqueous acid solution.

Original language	English
Pages (from-to)	551-555
Number of pages	5
Journal	Dalton Transactions
DOIs	https://doi.org/10.1039/J29660000551
Publication status	Published - 1966
Externally published	Yes

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title = "Alkyl hydrogen sulphates. Part II. The hydrolysis in aqueous acid solution",

abstract = "Oxygen-18 tracer studies were carried out on the hydrolysis of sodium methyl, ethyl, and isopropyl sulphates in aqueous perchloric acid and sodium hydroxide solutions. The reaction proceeds by sulphur-oxygen bond fission in acid solution and carbon-oxygen bond fission in alkaline solution. An A-1 mechanism is proposed for the hydrolysis reaction in aqueous acid solution.",

author = "Batts, {B. D.}",

year = "1966",

doi = "10.1039/J29660000551",

language = "English",

pages = "551--555",

journal = "Dalton Transactions",

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T1 - Alkyl hydrogen sulphates. Part II. The hydrolysis in aqueous acid solution

AU - Batts, B. D.

PY - 1966

Y1 - 1966

N2 - Oxygen-18 tracer studies were carried out on the hydrolysis of sodium methyl, ethyl, and isopropyl sulphates in aqueous perchloric acid and sodium hydroxide solutions. The reaction proceeds by sulphur-oxygen bond fission in acid solution and carbon-oxygen bond fission in alkaline solution. An A-1 mechanism is proposed for the hydrolysis reaction in aqueous acid solution.

AB - Oxygen-18 tracer studies were carried out on the hydrolysis of sodium methyl, ethyl, and isopropyl sulphates in aqueous perchloric acid and sodium hydroxide solutions. The reaction proceeds by sulphur-oxygen bond fission in acid solution and carbon-oxygen bond fission in alkaline solution. An A-1 mechanism is proposed for the hydrolysis reaction in aqueous acid solution.

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U2 - 10.1039/J29660000551

DO - 10.1039/J29660000551

M3 - Article

AN - SCOPUS:11144304893

SN - 1477-9226

SP - 551

EP - 555

JO - Dalton Transactions

JF - Dalton Transactions

ER -

Alkyl hydrogen sulphates. Part II. The hydrolysis in aqueous acid solution

Abstract

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