Abstract
Oxygen-18 tracer studies were carried out on the hydrolysis of sodium methyl, ethyl, and isopropyl sulphates in aqueous perchloric acid and sodium hydroxide solutions. The reaction proceeds by sulphur-oxygen bond fission in acid solution and carbon-oxygen bond fission in alkaline solution. An A-1 mechanism is proposed for the hydrolysis reaction in aqueous acid solution.
| Original language | English |
|---|---|
| Pages (from-to) | 551-555 |
| Number of pages | 5 |
| Journal | Dalton Transactions |
| DOIs | |
| Publication status | Published - 1966 |
| Externally published | Yes |
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