An extension of the quadrant rule in oxiranes to non-alkyl substituents: the CD of R (-)- and S (+)-epichlorohydrin

Anat Basil; Sara Ben-Tzur; Aharon Gedanken; Alison Rodger

doi:10.1016/0009-2614(91)85154-O

An extension of the quadrant rule in oxiranes to non-alkyl substituents: the CD of R (-)- and S (+)-epichlorohydrin

Anat Basil^*, Sara Ben-Tzur, Aharon Gedanken, Alison Rodger

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The circular dichroism (CD) of epichlorohydrin (1-chloro-2,3-epoxypropane) in the gas phase reveals one structureless broad band peaked at 1710 Å. The CD sign of this band is according to the prediction made by the quadrant rule previously established for the oxirane chromophore. It seems that the quadrant rule can be applied to substituents other than alkyl groups.

Original language	English
Pages (from-to)	482-484
Number of pages	3
Journal	Chemical Physics Letters
Volume	180
Issue number	5
DOIs	https://doi.org/10.1016/0009-2614(91)85154-O
Publication status	Published - 31 May 1991
Externally published	Yes

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abstract = "The circular dichroism (CD) of epichlorohydrin (1-chloro-2,3-epoxypropane) in the gas phase reveals one structureless broad band peaked at 1710 {\AA}. The CD sign of this band is according to the prediction made by the quadrant rule previously established for the oxirane chromophore. It seems that the quadrant rule can be applied to substituents other than alkyl groups.",

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AU - Ben-Tzur, Sara

AU - Gedanken, Aharon

AU - Rodger, Alison

PY - 1991/5/31

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N2 - The circular dichroism (CD) of epichlorohydrin (1-chloro-2,3-epoxypropane) in the gas phase reveals one structureless broad band peaked at 1710 Å. The CD sign of this band is according to the prediction made by the quadrant rule previously established for the oxirane chromophore. It seems that the quadrant rule can be applied to substituents other than alkyl groups.

AB - The circular dichroism (CD) of epichlorohydrin (1-chloro-2,3-epoxypropane) in the gas phase reveals one structureless broad band peaked at 1710 Å. The CD sign of this band is according to the prediction made by the quadrant rule previously established for the oxirane chromophore. It seems that the quadrant rule can be applied to substituents other than alkyl groups.

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An extension of the quadrant rule in oxiranes to non-alkyl substituents: the CD of R (-)- and S (+)-epichlorohydrin

Abstract

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