An iron-capped metal-organic polyyne

{[Fe](C≡C)2[W] ≡CC≡CC≡[W](C≡C)2[Fe]}

Sergey N. Semenov, Shiva F. Taghipourian, Olivier Blacque, Thomas Fox, Koushik Venkatesan, Heinz Berke*

*Corresponding author for this work

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

The organometallic conjugated complex H(C≡C)2[W] ≡CC≡CC≡[W](C≡C)2H {[W]=W(dppe)2; dppe = 1,2-bis(diphenylphosphino)ethane} containing a ditungstenatetradecaheptayne unit was synthesized by utilizing a new and efficient coupling method. The stannylated derivative was converted to the tetranuclear complex, which exhibits efficient long-range electron transfer.

Original languageEnglish
Pages (from-to)7584-7585
Number of pages2
JournalJournal of the American Chemical Society
Volume132
Issue number22
DOIs
Publication statusPublished - 9 Jun 2010
Externally publishedYes

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