Abstract
1,1′-Bis(trifluorovinyl)ferrocene is obtained in excellent yields from a Negishi type coupling reaction. Under certain redox conditions and in the presence of a suitable nucleophile, the highly reactive compound undergoes a transformation to fluorinated ferrocenophanes. Intra and intermolecular [2+2]-cycloaddition products are formed upon heating.
Original language | English |
---|---|
Pages (from-to) | 7239-7241 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 47 |
Issue number | 25 |
DOIs | |
Publication status | Published - 2011 |
Externally published | Yes |