Azulene based metal-organic frameworks for strong adsorption of H 2

Samir Barman; Hiroyasu Furukawa; Olivier Blacque; Koushik Venkatesan; Omar M. Yaghi; Heinz Berke

doi:10.1039/c0cc02589e

Azulene based metal-organic frameworks for strong adsorption of H 2

Samir Barman, Hiroyasu Furukawa^*, Olivier Blacque, Koushik Venkatesan, Omar M. Yaghi, Heinz Berke

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H₂ interactions (7.8-6.8 kJ mol^-1), which revealed the significant impact of internally polarized azulene backbone to stabilized H₂ molecules in the framework.

Original language	English
Pages (from-to)	7981-7983
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	42
DOIs	https://doi.org/10.1039/c0cc02589e
Publication status	Published - 14 Nov 2010
Externally published	Yes

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title = "Azulene based metal-organic frameworks for strong adsorption of H 2 ",

abstract = "Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H2 interactions (7.8-6.8 kJ mol-1), which revealed the significant impact of internally polarized azulene backbone to stabilized H2 molecules in the framework.",

author = "Samir Barman and Hiroyasu Furukawa and Olivier Blacque and Koushik Venkatesan and Yaghi, {Omar M.} and Heinz Berke",

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T1 - Azulene based metal-organic frameworks for strong adsorption of H 2

AU - Barman, Samir

AU - Furukawa, Hiroyasu

AU - Blacque, Olivier

AU - Venkatesan, Koushik

AU - Yaghi, Omar M.

AU - Berke, Heinz

PY - 2010/11/14

Y1 - 2010/11/14

N2 - Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H2 interactions (7.8-6.8 kJ mol-1), which revealed the significant impact of internally polarized azulene backbone to stabilized H2 molecules in the framework.

AB - Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H2 interactions (7.8-6.8 kJ mol-1), which revealed the significant impact of internally polarized azulene backbone to stabilized H2 molecules in the framework.

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U2 - 10.1039/c0cc02589e

DO - 10.1039/c0cc02589e

M3 - Article

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AN - SCOPUS:77958506786

SN - 1359-7345

VL - 46

SP - 7981

EP - 7983

JO - Chemical Communications

JF - Chemical Communications

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ER -

Azulene based metal-organic frameworks for strong adsorption of H 2

Abstract

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