Biomarker signatures of Upper Cretaceous Latrobe Group hydrocarbon source rocks, Gippsland Basin, Australia: distribution and palaeoenvironment significance of aliphatic hydrocarbons

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Upper Cretaceous (Maastrichtian and Campanian) hydrocarbon source rocks from the Latrobe Group, Gippsland Basin (Australia) have been analysed using gas chromatography–mass spectrometry (GC–MS) in order to understand their geochemical characteristics and to reconstruct palaeovegetation and palaeoclimate changes. n-Alkanes ranging from C10 to C37 dominate the aliphatic hydrocarbons in the rock extracts. Both the carbon preference index and the odd-to-even predominance values of n-alkanes are higher than 1.0, suggesting an input from terrigenous higher plants. Low wax indices (mostly < 1.0) and a predominance of C29 over C27 steranes corroborate a major contribution from higher plants. High pristane/phytane (Pr/Ph) ratios (>3.0), a low gammacerane index (<0.3) and the Pr/n-C17 versus Ph/n-C18 cross-plot indicate that the Upper Cretaceous hydrocarbon source rocks were probably deposited in an oxidising environment with fresh water. Thermal maturity parameters such as sterane isomerisation ratios, C31 22S/(22S + 22R) homohopane, C30 αβ/(αβ + βα) hopane and 16(H) β/(α + β) phyllocladane, together with Tmax data and the presence of C27 17β(H)-22,29,30-trisnorhopane (βTm), suggest that most of samples have a relatively low maturity in the early to mid-oil generation window. Angiosperm- and gymnosperm-derived biomarkers, including labdane, pimarane, isopimarane, phyllocladane, abietane, rimuane, ent-beyerane, ent-kaurane, oleanane, 10β(H)-des-A-oleanane, 10β(H)-des-A-lupane, and 10β(H)-des-A-ursane, suggest that palaeovegetation during the Upper Cretaceous was characterised by both gymnosperms (e.g. Araucariaceae and Podocarpaceae) and angiosperms (e.g. Nothofagus), but was dominated by gymnosperms. Compared with samples from the Campanian, there was a relatively lesser contribution from angiosperms during the Maastrichtian. This shows that the palaeoclimate was becoming cooler from the Campanian to the Maastrichtian, which is consistent with previous palynology evidence and sea-surface temperature estimates.

LanguageEnglish
Pages29-42
Number of pages14
JournalInternational Journal of Coal Geology
Volume196
DOIs
Publication statusPublished - 1 Aug 2018

Fingerprint

gymnosperm
aliphatic hydrocarbon
Biomarkers
Campanian
paleoenvironment
Maastrichtian
angiosperm
source rock
biomarker
Hydrocarbons
Rocks
hydrocarbon
Cretaceous
paleoclimate
alkane
Paraffins
basin
thermal maturity
Waxes
palynology

Keywords

  • Gippsland Basin
  • Upper Cretaceous
  • Biomarker
  • Palaeoenvironment
  • Palaeoflora

Cite this

@article{70b5766bae1d44cfb4fc0b33a134d63e,
title = "Biomarker signatures of Upper Cretaceous Latrobe Group hydrocarbon source rocks, Gippsland Basin, Australia: distribution and palaeoenvironment significance of aliphatic hydrocarbons",
abstract = "Upper Cretaceous (Maastrichtian and Campanian) hydrocarbon source rocks from the Latrobe Group, Gippsland Basin (Australia) have been analysed using gas chromatography–mass spectrometry (GC–MS) in order to understand their geochemical characteristics and to reconstruct palaeovegetation and palaeoclimate changes. n-Alkanes ranging from C10 to C37 dominate the aliphatic hydrocarbons in the rock extracts. Both the carbon preference index and the odd-to-even predominance values of n-alkanes are higher than 1.0, suggesting an input from terrigenous higher plants. Low wax indices (mostly < 1.0) and a predominance of C29 over C27 steranes corroborate a major contribution from higher plants. High pristane/phytane (Pr/Ph) ratios (>3.0), a low gammacerane index (<0.3) and the Pr/n-C17 versus Ph/n-C18 cross-plot indicate that the Upper Cretaceous hydrocarbon source rocks were probably deposited in an oxidising environment with fresh water. Thermal maturity parameters such as sterane isomerisation ratios, C31 22S/(22S + 22R) homohopane, C30 αβ/(αβ + βα) hopane and 16(H) β/(α + β) phyllocladane, together with Tmax data and the presence of C27 17β(H)-22,29,30-trisnorhopane (βTm), suggest that most of samples have a relatively low maturity in the early to mid-oil generation window. Angiosperm- and gymnosperm-derived biomarkers, including labdane, pimarane, isopimarane, phyllocladane, abietane, rimuane, ent-beyerane, ent-kaurane, oleanane, 10β(H)-des-A-oleanane, 10β(H)-des-A-lupane, and 10β(H)-des-A-ursane, suggest that palaeovegetation during the Upper Cretaceous was characterised by both gymnosperms (e.g. Araucariaceae and Podocarpaceae) and angiosperms (e.g. Nothofagus), but was dominated by gymnosperms. Compared with samples from the Campanian, there was a relatively lesser contribution from angiosperms during the Maastrichtian. This shows that the palaeoclimate was becoming cooler from the Campanian to the Maastrichtian, which is consistent with previous palynology evidence and sea-surface temperature estimates.",
keywords = "Gippsland Basin, Upper Cretaceous, Biomarker, Palaeoenvironment, Palaeoflora",
author = "Lian Jiang and George, {Simon C.}",
year = "2018",
month = "8",
day = "1",
doi = "10.1016/j.coal.2018.06.025",
language = "English",
volume = "196",
pages = "29--42",
journal = "International Journal of Coal Geology",
issn = "0166-5162",
publisher = "Elsevier",

}

TY - JOUR

T1 - Biomarker signatures of Upper Cretaceous Latrobe Group hydrocarbon source rocks, Gippsland Basin, Australia

T2 - International Journal of Coal Geology

AU - Jiang, Lian

AU - George, Simon C.

PY - 2018/8/1

Y1 - 2018/8/1

N2 - Upper Cretaceous (Maastrichtian and Campanian) hydrocarbon source rocks from the Latrobe Group, Gippsland Basin (Australia) have been analysed using gas chromatography–mass spectrometry (GC–MS) in order to understand their geochemical characteristics and to reconstruct palaeovegetation and palaeoclimate changes. n-Alkanes ranging from C10 to C37 dominate the aliphatic hydrocarbons in the rock extracts. Both the carbon preference index and the odd-to-even predominance values of n-alkanes are higher than 1.0, suggesting an input from terrigenous higher plants. Low wax indices (mostly < 1.0) and a predominance of C29 over C27 steranes corroborate a major contribution from higher plants. High pristane/phytane (Pr/Ph) ratios (>3.0), a low gammacerane index (<0.3) and the Pr/n-C17 versus Ph/n-C18 cross-plot indicate that the Upper Cretaceous hydrocarbon source rocks were probably deposited in an oxidising environment with fresh water. Thermal maturity parameters such as sterane isomerisation ratios, C31 22S/(22S + 22R) homohopane, C30 αβ/(αβ + βα) hopane and 16(H) β/(α + β) phyllocladane, together with Tmax data and the presence of C27 17β(H)-22,29,30-trisnorhopane (βTm), suggest that most of samples have a relatively low maturity in the early to mid-oil generation window. Angiosperm- and gymnosperm-derived biomarkers, including labdane, pimarane, isopimarane, phyllocladane, abietane, rimuane, ent-beyerane, ent-kaurane, oleanane, 10β(H)-des-A-oleanane, 10β(H)-des-A-lupane, and 10β(H)-des-A-ursane, suggest that palaeovegetation during the Upper Cretaceous was characterised by both gymnosperms (e.g. Araucariaceae and Podocarpaceae) and angiosperms (e.g. Nothofagus), but was dominated by gymnosperms. Compared with samples from the Campanian, there was a relatively lesser contribution from angiosperms during the Maastrichtian. This shows that the palaeoclimate was becoming cooler from the Campanian to the Maastrichtian, which is consistent with previous palynology evidence and sea-surface temperature estimates.

AB - Upper Cretaceous (Maastrichtian and Campanian) hydrocarbon source rocks from the Latrobe Group, Gippsland Basin (Australia) have been analysed using gas chromatography–mass spectrometry (GC–MS) in order to understand their geochemical characteristics and to reconstruct palaeovegetation and palaeoclimate changes. n-Alkanes ranging from C10 to C37 dominate the aliphatic hydrocarbons in the rock extracts. Both the carbon preference index and the odd-to-even predominance values of n-alkanes are higher than 1.0, suggesting an input from terrigenous higher plants. Low wax indices (mostly < 1.0) and a predominance of C29 over C27 steranes corroborate a major contribution from higher plants. High pristane/phytane (Pr/Ph) ratios (>3.0), a low gammacerane index (<0.3) and the Pr/n-C17 versus Ph/n-C18 cross-plot indicate that the Upper Cretaceous hydrocarbon source rocks were probably deposited in an oxidising environment with fresh water. Thermal maturity parameters such as sterane isomerisation ratios, C31 22S/(22S + 22R) homohopane, C30 αβ/(αβ + βα) hopane and 16(H) β/(α + β) phyllocladane, together with Tmax data and the presence of C27 17β(H)-22,29,30-trisnorhopane (βTm), suggest that most of samples have a relatively low maturity in the early to mid-oil generation window. Angiosperm- and gymnosperm-derived biomarkers, including labdane, pimarane, isopimarane, phyllocladane, abietane, rimuane, ent-beyerane, ent-kaurane, oleanane, 10β(H)-des-A-oleanane, 10β(H)-des-A-lupane, and 10β(H)-des-A-ursane, suggest that palaeovegetation during the Upper Cretaceous was characterised by both gymnosperms (e.g. Araucariaceae and Podocarpaceae) and angiosperms (e.g. Nothofagus), but was dominated by gymnosperms. Compared with samples from the Campanian, there was a relatively lesser contribution from angiosperms during the Maastrichtian. This shows that the palaeoclimate was becoming cooler from the Campanian to the Maastrichtian, which is consistent with previous palynology evidence and sea-surface temperature estimates.

KW - Gippsland Basin

KW - Upper Cretaceous

KW - Biomarker

KW - Palaeoenvironment

KW - Palaeoflora

UR - http://www.scopus.com/inward/record.url?scp=85049750418&partnerID=8YFLogxK

U2 - 10.1016/j.coal.2018.06.025

DO - 10.1016/j.coal.2018.06.025

M3 - Article

VL - 196

SP - 29

EP - 42

JO - International Journal of Coal Geology

JF - International Journal of Coal Geology

SN - 0166-5162

ER -