Biosynthesis and structural revision of neomarinone

John A. Kalaitzis, Yoshimitsu Hamano, George Nilsen, Bradley S. Moore*

*Corresponding author for this work

Research output: Contribution to journalLetter

44 Citations (Scopus)

Abstract

(Equation presented) The biosynthesis of the meroterpenoid neomarinone from a marine actinomycete was probed through feeding experiments with 13C-labeled precursors. NMR characterization of [U-13C 6]glucose-enriched neomarinone led to the structural revision of structure 4a to 4b, which was confirmed by extensive 2D NMR spectrometry with unlabeled compound.

Original languageEnglish
Pages (from-to)4449-4452
Number of pages4
JournalOrganic Letters
Volume5
Issue number23
DOIs
Publication statusPublished - 2003
Externally publishedYes

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