Bipolenins K-N

new sesquiterpenoids from the fungal plant pathogen Bipolaris sorokiniana

Chin-Soon Phan, Hang Li, Simon Kessler, Peter S. Solomon, Andrew M. Piggott*, Yit-Heng Chooi

*Corresponding author for this work

Research output: Contribution to journalArticle

1 Citation (Scopus)
3 Downloads (Pure)

Abstract

Chemical investigation of the barley and wheat fungal pathogen Bipolaris sorokiniana BRIP10943 yielded four new sativene-type sesquiterpenoid natural products, bipolenins K-N (1-4), together with seven related known analogues (5-11), and a sesterterpenoid (12). Their structures were determined by detailed analysis of spectroscopic data, supported by TDDFT calculations and comparison with previously reported analogues. These compounds were evaluated for their phytotoxic activity against wheat seedlings and wheat seed germination. The putative biosynthetic relationships between the isolated sesquiterpenoids were also explored.

Original languageEnglish
Pages (from-to)2020-2028
Number of pages9
JournalBeilstein Journal of Organic Chemistry
Volume15
DOIs
Publication statusPublished - 26 Aug 2019

Bibliographical note

Copyright the Author(s) 2019. Version archived for private and non-commercial use with the permission of the author/s and according to publisher conditions. For further rights please contact the publisher.

Keywords

  • Bipolaris sorokiniana
  • phytotoxicity
  • sesquiterpenes
  • terpenes

Fingerprint Dive into the research topics of 'Bipolenins K-N: new sesquiterpenoids from the fungal plant pathogen <i>Bipolaris sorokiniana</i>'. Together they form a unique fingerprint.

  • Cite this