Carbon-Carbon Bonds of Manganese Half-Sandwich Complexes for Electron Reservoir Functions

Koushik Venkatesan; Olivier Blacque; Thomas Fox; Montserrat Alfonso; Helmut W. Schmalle; Heinz Berke

doi:10.1021/om034237q

Carbon-Carbon Bonds of Manganese Half-Sandwich Complexes for Electron Reservoir Functions

Koushik Venkatesan, Olivier Blacque, Thomas Fox, Montserrat Alfonso, Helmut W. Schmalle, Heinz Berke^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Vinylidene species of the type Mn(C₅H₄CH ₃)[(H₃C)₂PCH₂CH₂P(CH ₃)₂](=C=CR¹R²) (R¹ = R² = H; R¹ = H, R² = Ph) can be fully reversibly coupled to yield the dinuclear complexes [(C₅H ₄CH₃)(dmpe)Mn≡ CC(R¹)(R ²)C(R¹)(R²)C≡Mn(dmpe)(C₅H ₄CH₃)[PF₆]₂(R¹, R ² = H; R¹ = H, R² = Ph) by an oxidation / reduction cycle involving formation and cleavage of a C-C σ bond.

Original language	English
Pages (from-to)	1183-1186
Number of pages	4
Journal	Organometallics
Volume	23
Issue number	6
DOIs	https://doi.org/10.1021/om034237q
Publication status	Published - 15 Mar 2004
Externally published	Yes

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title = "Carbon-Carbon Bonds of Manganese Half-Sandwich Complexes for Electron Reservoir Functions",

abstract = "Vinylidene species of the type Mn(C5H4CH 3)[(H3C)2PCH2CH2P(CH 3)2](=C=CR1R2) (R1 = R2 = H; R1 = H, R2 = Ph) can be fully reversibly coupled to yield the dinuclear complexes [(C5H 4CH3)(dmpe)Mn≡ CC(R1)(R 2)C(R1)(R2)C≡Mn(dmpe)(C5H 4CH3)[PF6]2(R1, R 2 = H; R1 = H, R2 = Ph) by an oxidation / reduction cycle involving formation and cleavage of a C-C σ bond.",

author = "Koushik Venkatesan and Olivier Blacque and Thomas Fox and Montserrat Alfonso and Schmalle, {Helmut W.} and Heinz Berke",

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doi = "10.1021/om034237q",

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volume = "23",

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journal = "Organometallics",

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T1 - Carbon-Carbon Bonds of Manganese Half-Sandwich Complexes for Electron Reservoir Functions

AU - Venkatesan, Koushik

AU - Blacque, Olivier

AU - Fox, Thomas

AU - Alfonso, Montserrat

AU - Schmalle, Helmut W.

AU - Berke, Heinz

PY - 2004/3/15

Y1 - 2004/3/15

N2 - Vinylidene species of the type Mn(C5H4CH 3)[(H3C)2PCH2CH2P(CH 3)2](=C=CR1R2) (R1 = R2 = H; R1 = H, R2 = Ph) can be fully reversibly coupled to yield the dinuclear complexes [(C5H 4CH3)(dmpe)Mn≡ CC(R1)(R 2)C(R1)(R2)C≡Mn(dmpe)(C5H 4CH3)[PF6]2(R1, R 2 = H; R1 = H, R2 = Ph) by an oxidation / reduction cycle involving formation and cleavage of a C-C σ bond.

AB - Vinylidene species of the type Mn(C5H4CH 3)[(H3C)2PCH2CH2P(CH 3)2](=C=CR1R2) (R1 = R2 = H; R1 = H, R2 = Ph) can be fully reversibly coupled to yield the dinuclear complexes [(C5H 4CH3)(dmpe)Mn≡ CC(R1)(R 2)C(R1)(R2)C≡Mn(dmpe)(C5H 4CH3)[PF6]2(R1, R 2 = H; R1 = H, R2 = Ph) by an oxidation / reduction cycle involving formation and cleavage of a C-C σ bond.

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U2 - 10.1021/om034237q

DO - 10.1021/om034237q

M3 - Article

AN - SCOPUS:1842534214

SN - 0276-7333

VL - 23

SP - 1183

EP - 1186

JO - Organometallics

JF - Organometallics

IS - 6

ER -

Carbon-Carbon Bonds of Manganese Half-Sandwich Complexes for Electron Reservoir Functions

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