CATHALYTIC OXIDATION. THE REACTION OF ETHYLENE OVER PD AND PD-AU ALLOYS

HR GERBERICH HR; NW CANT NW; WK HALL WK

CATHALYTIC OXIDATION. THE REACTION OF ETHYLENE OVER PD AND PD-AU ALLOYS

HR GERBERICH HR^*, NW CANT NW, WK HALL WK

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The gross kinetics for the oxidation of ethylene were determined over Pd and Pd-Au alloys in a steady state flow reactor and in a recirculating reactor, stripping the products with each pass. The partial oxidation products over Pd included acetic acid, acetic anhydride, acetaldehyde and (a trace) ethylene oxide. Selectivity for partial oxidation varied from 25 to 40%. Both the total rate and selectivity increased with O//2 pressure.

Original language	English
Journal	Amer Chem Soc, Div Petrol ChemNY
Volume	14
Issue number	4
Publication status	Published - 1969

Cite this

@article{94da2527c54d4a46a9baefd9a1bb68b9,

title = "CATHALYTIC OXIDATION. THE REACTION OF ETHYLENE OVER PD AND PD-AU ALLOYS",

abstract = "The gross kinetics for the oxidation of ethylene were determined over Pd and Pd-Au alloys in a steady state flow reactor and in a recirculating reactor, stripping the products with each pass. The partial oxidation products over Pd included acetic acid, acetic anhydride, acetaldehyde and (a trace) ethylene oxide. Selectivity for partial oxidation varied from 25 to 40%. Both the total rate and selectivity increased with O//2 pressure.",

author = "{GERBERICH HR}, HR and {CANT NW}, NW and {HALL WK}, WK",

year = "1969",

language = "English",

volume = "14",

journal = "Amer Chem Soc, Div Petrol ChemNY",

issn = "0569-3799",

publisher = "American Chemical Society",

number = "4",

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T1 - CATHALYTIC OXIDATION. THE REACTION OF ETHYLENE OVER PD AND PD-AU ALLOYS

AU - GERBERICH HR, HR

AU - CANT NW, NW

AU - HALL WK, WK

PY - 1969

Y1 - 1969

N2 - The gross kinetics for the oxidation of ethylene were determined over Pd and Pd-Au alloys in a steady state flow reactor and in a recirculating reactor, stripping the products with each pass. The partial oxidation products over Pd included acetic acid, acetic anhydride, acetaldehyde and (a trace) ethylene oxide. Selectivity for partial oxidation varied from 25 to 40%. Both the total rate and selectivity increased with O//2 pressure.

AB - The gross kinetics for the oxidation of ethylene were determined over Pd and Pd-Au alloys in a steady state flow reactor and in a recirculating reactor, stripping the products with each pass. The partial oxidation products over Pd included acetic acid, acetic anhydride, acetaldehyde and (a trace) ethylene oxide. Selectivity for partial oxidation varied from 25 to 40%. Both the total rate and selectivity increased with O//2 pressure.

UR - http://www.scopus.com/inward/record.url?scp=0014658199&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0014658199

SN - 0569-3799

VL - 14

JO - Amer Chem Soc, Div Petrol ChemNY

JF - Amer Chem Soc, Div Petrol ChemNY

IS - 4

ER -

CATHALYTIC OXIDATION. THE REACTION OF ETHYLENE OVER PD AND PD-AU ALLOYS

Abstract

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