Chiral metal complexes. 51. * structure of the DNA probe Δ-α-[N,N′-dimethyl-1,6-di(2-pyridyl)-2,5-diazahexane][S- phenylalaninato(1-)]-cobalt(III) perchlorate

Peter Leverett; Janice Petherick; Peter A. Williams; Robert S. Vagg

Chiral metal complexes. 51. * structure of the DNA probe Δ-α-[N,N′-dimethyl-1,6-di(2-pyridyl)-2,5-diazahexane][S- phenylalaninato(1-)]-cobalt(III) perchlorate

Peter Leverett^*, Janice Petherick, Peter A. Williams, Robert S. Vagg

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The ternary complex Δ-α-[N,N′-dimethyl-1,6-di(2-pyridyl)-2,5-diazahexane][S- phenylalaninato(1-)]cobalt(III) perchlorate has been isolated from aqueous solution as the least soluble diastereoisomer. Crystals are orthorhombic, space group P2₁2₁2₁ with a-10.462(2), b = 12.895(3), c = 22.560(3)Å, V=3043.4Å3, Z = 4, D_c= 1.480 and D_m= 1.48. The structure was refined by full-matrix least-squares to a final R value of 0.054 for 1797 reflections with I > 2σ(I). In the structure, the phenyl ring of the phenylalanine ligand is bonded face-to-face, albeit slightly offset, to one of the pyridine rings of the tetradentate. ¹H NMR measurements show that this indicated weak interaction between the rings persists in solution.

Original language	English
Pages (from-to)	91-100
Number of pages	10
Journal	Journal of Coordination Chemistry
Volume	49
Issue number	2
Publication status	Published - 1999

Keywords

Cobalt(III)
DNA
Phenylalanine
Tetradentate
Van der waals bond
X-ray structure

Cite this

@article{d1db61e3744343feb0034da7d0a5cda2,

title = "Chiral metal complexes. 51. * structure of the DNA probe Δ-α-[N,N′-dimethyl-1,6-di(2-pyridyl)-2,5-diazahexane][S- phenylalaninato(1-)]-cobalt(III) perchlorate",

abstract = "The ternary complex Δ-α-[N,N′-dimethyl-1,6-di(2-pyridyl)-2,5-diazahexane][S- phenylalaninato(1-)]cobalt(III) perchlorate has been isolated from aqueous solution as the least soluble diastereoisomer. Crystals are orthorhombic, space group P212121 with a-10.462(2), b = 12.895(3), c = 22.560(3){\AA}, V=3043.4{\AA}3, Z = 4, Dc= 1.480 and Dm= 1.48. The structure was refined by full-matrix least-squares to a final R value of 0.054 for 1797 reflections with I > 2σ(I). In the structure, the phenyl ring of the phenylalanine ligand is bonded face-to-face, albeit slightly offset, to one of the pyridine rings of the tetradentate. 1H NMR measurements show that this indicated weak interaction between the rings persists in solution.",

keywords = "Cobalt(III), DNA, Phenylalanine, Tetradentate, Van der waals bond, X-ray structure",

author = "Peter Leverett and Janice Petherick and Williams, {Peter A.} and Vagg, {Robert S.}",

year = "1999",

language = "English",

volume = "49",

pages = "91--100",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Gordon Breach Science Publishing",

number = "2",

}

TY - JOUR

T1 - Chiral metal complexes. 51. * structure of the DNA probe Δ-α-[N,N′-dimethyl-1,6-di(2-pyridyl)-2,5-diazahexane][S- phenylalaninato(1-)]-cobalt(III) perchlorate

AU - Leverett, Peter

AU - Petherick, Janice

AU - Williams, Peter A.

AU - Vagg, Robert S.

PY - 1999

Y1 - 1999

N2 - The ternary complex Δ-α-[N,N′-dimethyl-1,6-di(2-pyridyl)-2,5-diazahexane][S- phenylalaninato(1-)]cobalt(III) perchlorate has been isolated from aqueous solution as the least soluble diastereoisomer. Crystals are orthorhombic, space group P212121 with a-10.462(2), b = 12.895(3), c = 22.560(3)Å, V=3043.4Å3, Z = 4, Dc= 1.480 and Dm= 1.48. The structure was refined by full-matrix least-squares to a final R value of 0.054 for 1797 reflections with I > 2σ(I). In the structure, the phenyl ring of the phenylalanine ligand is bonded face-to-face, albeit slightly offset, to one of the pyridine rings of the tetradentate. 1H NMR measurements show that this indicated weak interaction between the rings persists in solution.

AB - The ternary complex Δ-α-[N,N′-dimethyl-1,6-di(2-pyridyl)-2,5-diazahexane][S- phenylalaninato(1-)]cobalt(III) perchlorate has been isolated from aqueous solution as the least soluble diastereoisomer. Crystals are orthorhombic, space group P212121 with a-10.462(2), b = 12.895(3), c = 22.560(3)Å, V=3043.4Å3, Z = 4, Dc= 1.480 and Dm= 1.48. The structure was refined by full-matrix least-squares to a final R value of 0.054 for 1797 reflections with I > 2σ(I). In the structure, the phenyl ring of the phenylalanine ligand is bonded face-to-face, albeit slightly offset, to one of the pyridine rings of the tetradentate. 1H NMR measurements show that this indicated weak interaction between the rings persists in solution.

KW - Cobalt(III)

KW - DNA

KW - Phenylalanine

KW - Tetradentate

KW - Van der waals bond

KW - X-ray structure

UR - http://www.scopus.com/inward/record.url?scp=8744278306&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:8744278306

SN - 0095-8972

VL - 49

SP - 91

EP - 100

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 2

ER -

Chiral metal complexes. 51. * structure of the DNA probe Δ-α-[N,N′-dimethyl-1,6-di(2-pyridyl)-2,5-diazahexane][S- phenylalaninato(1-)]-cobalt(III) perchlorate

Abstract

Keywords

Other files and links

Fingerprint

Cite this