Chiral shielding in nuclear magnetic resonance spectroscopy

Peter J. Stiles

doi:10.1071/CH9791375

Chiral shielding in nuclear magnetic resonance spectroscopy

Peter J. Stiles^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

A novel van der Waals shielding mechanism is discussed which contributes to the magnetic shielding non-equivalence of optical isomers of one chiral species in the presence of a second optically active species. It is more direct than standard mechanisms which invoke stereospecific association of the interacting molecules but appears to be of marginal experimental significance.

Original language	English
Pages (from-to)	1375-1377
Number of pages	3
Journal	Australian Journal of Chemistry
Volume	32
Issue number	6
DOIs	https://doi.org/10.1071/CH9791375
Publication status	Published - 1979

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title = "Chiral shielding in nuclear magnetic resonance spectroscopy",

abstract = "A novel van der Waals shielding mechanism is discussed which contributes to the magnetic shielding non-equivalence of optical isomers of one chiral species in the presence of a second optically active species. It is more direct than standard mechanisms which invoke stereospecific association of the interacting molecules but appears to be of marginal experimental significance.",

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AB - A novel van der Waals shielding mechanism is discussed which contributes to the magnetic shielding non-equivalence of optical isomers of one chiral species in the presence of a second optically active species. It is more direct than standard mechanisms which invoke stereospecific association of the interacting molecules but appears to be of marginal experimental significance.

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DO - 10.1071/CH9791375

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VL - 32

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EP - 1377

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 6

ER -

Chiral shielding in nuclear magnetic resonance spectroscopy

Abstract

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