Circular dichroism of D2d molecules in chiral environments promoted by Jahn-Teller Coupling

D. P. Craig*, P. J. Stiles

*Corresponding author for this work

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Molecules of symmetry D2d and S4 are achiral but following excitation to their orbitally degenerate electronic states are Jahn-Teller unstable and may deform to new equilibrium structures which are chiral. Enantiometric species are formed with equal propability. In the presence of added chiral molecules the exact equivalence of energy levels between enantiomers is destroyed. Vibronic transitions to the differentially perturbed excited states should display circular dichroism of readily measurable strength.

Original languageEnglish
Pages (from-to)225-227
Number of pages3
JournalChemical Physics Letters
Volume41
Issue number2
DOIs
Publication statusPublished - 15 Jul 1976
Externally publishedYes

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