Circular dichroism of oxiranes: An independent systems/perturbation approach

Alison Rodger*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

The circular dichroism (CD) spectra of the first two Rydberg transitions of alkyl-substituted oxiranes are interpreted by an independent systems/perturbation approach. When alkyloxirane compounds are treated as an achiral oxirane ring perturbed by alkyl substituents, quantitative relationships between CD and oxirane structure are obtained. The dipolar coupled-oscillator model of Kirkwood and Kuhn proves to be the only significant mechanism for both the n(0) → 3s and n(0) → 3p transitions. The static coupling model suggested by Gedanken et al. to account for the sign of the n(0) → 3s transition does not account for the variation in CD magnitudes that is observed.

Original languageEnglish
Pages (from-to)5941-5945
Number of pages5
JournalJournal of the American Chemical Society
Volume110
Issue number18
Publication statusPublished - 1988
Externally publishedYes

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