Cobalt(II) complexes of 2,3,5,6-Tetrakis(2-pyridyl)pyrazine and 2,4,6-Tris-(2-pyridyl)-1,3,5-triazine

H. A. Goodwin; R. N. Sylva; R. S. Vagg; E. C. Watton

doi:10.1071/CH9691605

Cobalt(II) complexes of 2,3,5,6-Tetrakis(2-pyridyl)pyrazine and 2,4,6-Tris-(2-pyridyl)-1,3,5-triazine

H. A. Goodwin^*, R. N. Sylva, R. S. Vagg, E. C. Watton

^*Corresponding author for this work

Macquarie University

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Bis-ligand cobalt(II) complexes of 2,4,6-tris(2-pyridyl)-1,3,5-triazine and 2,3,5,6.tetrakis(2-pyridyl)pyrazine have been prepared. The conductivities of the complexes in nitromethane solution correspond to values expected for bi-unielectrolytes. The temperature dependence of their magnetism has shown that in some instances there exists a spin-state equilibrium in the metal atom while in others the metal atom is spin-free and Curie-Weiss laws are obeyed.

Original language	English
Pages (from-to)	1605-1611
Number of pages	7
Journal	Australian Journal of Chemistry
Volume	22
Issue number	8
DOIs	https://doi.org/10.1071/CH9691605
Publication status	Published - 1969

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title = "Cobalt(II) complexes of 2,3,5,6-Tetrakis(2-pyridyl)pyrazine and 2,4,6-Tris-(2-pyridyl)-1,3,5-triazine",

abstract = "Bis-ligand cobalt(II) complexes of 2,4,6-tris(2-pyridyl)-1,3,5-triazine and 2,3,5,6.tetrakis(2-pyridyl)pyrazine have been prepared. The conductivities of the complexes in nitromethane solution correspond to values expected for bi-unielectrolytes. The temperature dependence of their magnetism has shown that in some instances there exists a spin-state equilibrium in the metal atom while in others the metal atom is spin-free and Curie-Weiss laws are obeyed.",

author = "Goodwin, {H. A.} and Sylva, {R. N.} and Vagg, {R. S.} and Watton, {E. C.}",

year = "1969",

doi = "10.1071/CH9691605",

language = "English",

volume = "22",

pages = "1605--1611",

journal = "Australian Journal of Chemistry",

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T1 - Cobalt(II) complexes of 2,3,5,6-Tetrakis(2-pyridyl)pyrazine and 2,4,6-Tris-(2-pyridyl)-1,3,5-triazine

AU - Goodwin, H. A.

AU - Sylva, R. N.

AU - Vagg, R. S.

AU - Watton, E. C.

PY - 1969

Y1 - 1969

N2 - Bis-ligand cobalt(II) complexes of 2,4,6-tris(2-pyridyl)-1,3,5-triazine and 2,3,5,6.tetrakis(2-pyridyl)pyrazine have been prepared. The conductivities of the complexes in nitromethane solution correspond to values expected for bi-unielectrolytes. The temperature dependence of their magnetism has shown that in some instances there exists a spin-state equilibrium in the metal atom while in others the metal atom is spin-free and Curie-Weiss laws are obeyed.

AB - Bis-ligand cobalt(II) complexes of 2,4,6-tris(2-pyridyl)-1,3,5-triazine and 2,3,5,6.tetrakis(2-pyridyl)pyrazine have been prepared. The conductivities of the complexes in nitromethane solution correspond to values expected for bi-unielectrolytes. The temperature dependence of their magnetism has shown that in some instances there exists a spin-state equilibrium in the metal atom while in others the metal atom is spin-free and Curie-Weiss laws are obeyed.

UR - http://www.scopus.com/inward/record.url?scp=84970609809&partnerID=8YFLogxK

U2 - 10.1071/CH9691605

DO - 10.1071/CH9691605

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SN - 0004-9425

VL - 22

SP - 1605

EP - 1611

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 8

ER -

Cobalt(II) complexes of 2,3,5,6-Tetrakis(2-pyridyl)pyrazine and 2,4,6-Tris-(2-pyridyl)-1,3,5-triazine

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