Collision-induced state-to-state energy transfer in the v 2+3v3 rovibrational manifold of gas-phase acetylene

A. P. Milce*, H. -D. Barth, B. J. Orr

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    33 Citations (Scopus)

    Abstract

    Time-resolved infrared-ultraviolet double resonance spectroscopy is used to measure collision-induced rovibrational energy transfer in the v 2+3v3 region (∼11 600 cm-1) of gas-phase acetylene. Of particular interest is rotationally resolved V-V transfer between the Fermi-coupled 2133 and 112 34351 levels, for which the rate is relatively high (approximately 13% of the Lennard-Jones collision rate) and the relevant rovibrational states markedly perturbed.

    Original languageEnglish
    Pages (from-to)2398-2401
    Number of pages4
    JournalThe Journal of Chemical Physics
    Volume100
    Issue number3
    DOIs
    Publication statusPublished - 1994

    Fingerprint

    Dive into the research topics of 'Collision-induced state-to-state energy transfer in the v 2+3v3 rovibrational manifold of gas-phase acetylene'. Together they form a unique fingerprint.

    Cite this