Configurations of glycosidic phosphates of lipopolysaccharide from Salmonella minnesota R595

Michael Batley; Nicolle H. Packer; John W. Redmond

doi:10.1021/bi00268a040

Configurations of glycosidic phosphates of lipopolysaccharide from Salmonella minnesota R595

Michael Batley^*, Nicolle H. Packer, John W. Redmond

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The anomeric configurations of the reducing terminal glucosamine and 4-amino-4-deoxy-L-arabinose phosphates in lipopolysaccharide from Salmonella minnesota R595 have been determined by nuclear magnetic resonance. Chemical shifts for the anomeric protons were obtained by selective decoupling of the phosphorus spectrum and proton-proton coupling constants by polarization transfer from protons to phosphorus. In both cases, the phosphate is attached to the sugar in an axial orientation.

Original language	English
Pages (from-to)	6580-6586
Number of pages	7
Journal	Biochemistry
Volume	21
Issue number	25
DOIs	https://doi.org/10.1021/bi00268a040
Publication status	Published - 1982

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title = "Configurations of glycosidic phosphates of lipopolysaccharide from Salmonella minnesota R595",

abstract = "The anomeric configurations of the reducing terminal glucosamine and 4-amino-4-deoxy-L-arabinose phosphates in lipopolysaccharide from Salmonella minnesota R595 have been determined by nuclear magnetic resonance. Chemical shifts for the anomeric protons were obtained by selective decoupling of the phosphorus spectrum and proton-proton coupling constants by polarization transfer from protons to phosphorus. In both cases, the phosphate is attached to the sugar in an axial orientation.",

author = "Michael Batley and Packer, {Nicolle H.} and Redmond, {John W.}",

year = "1982",

doi = "10.1021/bi00268a040",

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T1 - Configurations of glycosidic phosphates of lipopolysaccharide from Salmonella minnesota R595

AU - Batley, Michael

AU - Packer, Nicolle H.

AU - Redmond, John W.

PY - 1982

Y1 - 1982

N2 - The anomeric configurations of the reducing terminal glucosamine and 4-amino-4-deoxy-L-arabinose phosphates in lipopolysaccharide from Salmonella minnesota R595 have been determined by nuclear magnetic resonance. Chemical shifts for the anomeric protons were obtained by selective decoupling of the phosphorus spectrum and proton-proton coupling constants by polarization transfer from protons to phosphorus. In both cases, the phosphate is attached to the sugar in an axial orientation.

AB - The anomeric configurations of the reducing terminal glucosamine and 4-amino-4-deoxy-L-arabinose phosphates in lipopolysaccharide from Salmonella minnesota R595 have been determined by nuclear magnetic resonance. Chemical shifts for the anomeric protons were obtained by selective decoupling of the phosphorus spectrum and proton-proton coupling constants by polarization transfer from protons to phosphorus. In both cases, the phosphate is attached to the sugar in an axial orientation.

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U2 - 10.1021/bi00268a040

DO - 10.1021/bi00268a040

M3 - Article

C2 - 7150577

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EP - 6586

JO - Biochemistry

JF - Biochemistry

SN - 0006-2960

IS - 25

ER -

Configurations of glycosidic phosphates of lipopolysaccharide from Salmonella minnesota R595

Abstract

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