Contributions from dielectric inhomogeneity to the free energy of ionic solvation

Peter J. Stiles*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    5 Citations (Scopus)

    Abstract

    A new dielectric profile for the solvent dielectric constant beyond the primary coordination or solvation sphere is used to show that neglect of dielectric inhomogeneity by the Born treatment can lead to significant overestimation of ionic solvation energies.

    Original languageEnglish
    Pages (from-to)1389-1391
    Number of pages3
    JournalAustralian Journal of Chemistry
    Volume33
    Issue number6
    DOIs
    Publication statusPublished - 1980

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