Contributions from dielectric inhomogeneity to the free energy of ionic solvation

Peter J. Stiles

doi:10.1071/CH9801389

Contributions from dielectric inhomogeneity to the free energy of ionic solvation

Peter J. Stiles^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A new dielectric profile for the solvent dielectric constant beyond the primary coordination or solvation sphere is used to show that neglect of dielectric inhomogeneity by the Born treatment can lead to significant overestimation of ionic solvation energies.

Original language	English
Pages (from-to)	1389-1391
Number of pages	3
Journal	Australian Journal of Chemistry
Volume	33
Issue number	6
DOIs	https://doi.org/10.1071/CH9801389
Publication status	Published - 1980

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Contributions from dielectric inhomogeneity to the free energy of ionic solvation

Abstract

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