Contributions from dielectric inhomogeneity to the free energy of ionic solvation

Peter J. Stiles*

*Corresponding author for this work

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

A new dielectric profile for the solvent dielectric constant beyond the primary coordination or solvation sphere is used to show that neglect of dielectric inhomogeneity by the Born treatment can lead to significant overestimation of ionic solvation energies.

Original languageEnglish
Pages (from-to)1389-1391
Number of pages3
JournalAustralian Journal of Chemistry
Volume33
Issue number6
DOIs
Publication statusPublished - 1980

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