TY - JOUR
T1 - Correlation of 1H and 13C NMR spectra by selective inverse INEPT. Assignment of the proton and carbon spectra of methyl (5R*, 6S*,8Z,11Z,14Z)‐5,6‐epoxyeicosa‐8,11,14‐ trienoate
AU - Crossley, Maxwell J.
AU - Field, Leslie D.
AU - Gosper, Jeffrey J.
AU - Messerle, Barbara A.
PY - 1987
Y1 - 1987
N2 - Selective inverse INEPT and 13C → 1H → 1H heteronuclear relayed coherence transfer pulse sequences were employed to assign and correlate the proton and carbon NMR spectra of methyl (5R*,6S*,8Z,11 Z,14Z)‐5,6‐epoxyeicosa 8,11,14‐trienoate. The transfer of coherence from specific carbon nuclei in the molecule to protons was employed as a one‐dimensional method to correlate carbon and proton resonances. The one‐dimensional C→H coherence transfer experiments are particularly useful for C‐H correlation in situations where only a small amount of sample is available and two‐dimensional methods are only marginally applicable or impractical.
AB - Selective inverse INEPT and 13C → 1H → 1H heteronuclear relayed coherence transfer pulse sequences were employed to assign and correlate the proton and carbon NMR spectra of methyl (5R*,6S*,8Z,11 Z,14Z)‐5,6‐epoxyeicosa 8,11,14‐trienoate. The transfer of coherence from specific carbon nuclei in the molecule to protons was employed as a one‐dimensional method to correlate carbon and proton resonances. The one‐dimensional C→H coherence transfer experiments are particularly useful for C‐H correlation in situations where only a small amount of sample is available and two‐dimensional methods are only marginally applicable or impractical.
UR - http://www.scopus.com/inward/record.url?scp=84989643012&partnerID=8YFLogxK
U2 - 10.1002/mrc.1260250404
DO - 10.1002/mrc.1260250404
M3 - Article
AN - SCOPUS:84989643012
VL - 25
SP - 297
EP - 300
JO - Organic Magnetic Resonance
JF - Organic Magnetic Resonance
SN - 0030-4921
IS - 4
ER -