Crystal structure of poly[[μ3-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)]

Mohan Madhav Bhadbhade; Alexander J. Charlson

doi:10.1107/S2056989017016164

Crystal structure of poly[[μ₃-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)]

Mohan Madhav Bhadbhade, Alexander J. Charlson^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

The structure of the title compound, [CsPd(C₃H₆NO₃)Cl₂]_n, previously shown to have anticancer activity in rodent test systems and recently found to have antifungal activity, has been determined. The Pd centre is in a square-planar coordination environment with two chlorine atoms in cis positions and the remaining two coordination sites being coordinated by N and O atoms from deprotonated L-serine. Each of the Cs cations shows ninefold coordination with six chlorine and three O atoms resulting in a coordination environment that is similar to the well known Cs₂SO₄ structure. X-ray crystal structures of only three dichloridopalladium(II)–amino acid complexes have been determined so far and the present paper describes one of those.

Original language	English
Pages (from-to)	1898-1902
Number of pages	9
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	73
Issue number	12
DOIs	https://doi.org/10.1107/S2056989017016164
Publication status	Published - Dec 2017

Bibliographical note

Version archived for private and non-commercial use with the permission of the author/s and according to publisher conditions. For further rights please contact the publisher.

Plus 4 pages supporting information.

Keywords

palladium–amino acid complex
L-serine
single-crystal X-ray structure
palladium complex

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10.1107/S2056989017016164Licence: CC BY

Publisher versionFinal published version, 759 KBLicence: CC BY

Cite this

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title = "Crystal structure of poly[[μ3-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)]",

abstract = "The structure of the title compound, [CsPd(C3H6NO3)Cl2]n, previously shown to have anticancer activity in rodent test systems and recently found to have antifungal activity, has been determined. The Pd centre is in a square-planar coordination environment with two chlorine atoms in cis positions and the remaining two coordination sites being coordinated by N and O atoms from deprotonated L-serine. Each of the Cs cations shows ninefold coordination with six chlorine and three O atoms resulting in a coordination environment that is similar to the well known Cs2SO4 structure. X-ray crystal structures of only three dichloridopalladium(II)–amino acid complexes have been determined so far and the present paper describes one of those.",

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AB - The structure of the title compound, [CsPd(C3H6NO3)Cl2]n, previously shown to have anticancer activity in rodent test systems and recently found to have antifungal activity, has been determined. The Pd centre is in a square-planar coordination environment with two chlorine atoms in cis positions and the remaining two coordination sites being coordinated by N and O atoms from deprotonated L-serine. Each of the Cs cations shows ninefold coordination with six chlorine and three O atoms resulting in a coordination environment that is similar to the well known Cs2SO4 structure. X-ray crystal structures of only three dichloridopalladium(II)–amino acid complexes have been determined so far and the present paper describes one of those.

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