Crystal structure of poly[[μ3-(S)-2-amino-3-hydroxypropanoato]-cis-di-μ-chlorido-caesiumpalladium(II)]

Mohan Madhav Bhadbhade, Alexander J. Charlson*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

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    Abstract

    The structure of the title compound, [CsPd(C3H6NO3)Cl2]n, previously shown to have anti­cancer activity in rodent test systems and recently found to have anti­fungal activity, has been determined. The Pd centre is in a square-planar coordination environment with two chlorine atoms in cis positions and the remaining two coordination sites being coordinated by N and O atoms from deprotonated L-serine. Each of the Cs cations shows ninefold coordination with six chlorine and three O atoms resulting in a coordination environment that is similar to the well known Cs2SO4 structure. X-ray crystal structures of only three di­chlorido­palladium(II)–amino acid complexes have been determined so far and the present paper describes one of those.

    Original languageEnglish
    Pages (from-to)1898-1902
    Number of pages9
    JournalActa Crystallographica Section E: Crystallographic Communications
    Volume73
    Issue number12
    DOIs
    Publication statusPublished - Dec 2017

    Bibliographical note

    Version archived for private and non-commercial use with the permission of the author/s and according to publisher conditions. For further rights please contact the publisher.

    Plus 4 pages supporting information.

    Keywords

    • palladium–amino acid complex
    • L-serine
    • single-crystal X-ray structure
    • palladium complex

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