Cymantrene- and ferrocene-based complexes with perfluorinated bridging moieties

Max Roemer; Peter Schmiel; Dieter Lentz

doi:10.1021/om2000053

Cymantrene- and ferrocene-based complexes with perfluorinated bridging moieties

Max Roemer, Peter Schmiel, Dieter Lentz^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Trifluorovinylcymantrene (1) and -ferrocene (2) form the basis of a versatile building block chemistry. Di- and trinuclear complexes with perfluorinated bridging moieties are obtained by [2+2] cycloaddition on 1 and nucleophilic substitution on the C₂F₃ unit of 2 with cymantrenyllithium.

Original language	English
Pages (from-to)	2063-2066
Number of pages	4
Journal	Organometallics
Volume	30
Issue number	7
DOIs	https://doi.org/10.1021/om2000053
Publication status	Published - 2011
Externally published	Yes

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10.1021/om2000053

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title = "Cymantrene- and ferrocene-based complexes with perfluorinated bridging moieties",

abstract = "Trifluorovinylcymantrene (1) and -ferrocene (2) form the basis of a versatile building block chemistry. Di- and trinuclear complexes with perfluorinated bridging moieties are obtained by [2+2] cycloaddition on 1 and nucleophilic substitution on the C2F3 unit of 2 with cymantrenyllithium.",

author = "Max Roemer and Peter Schmiel and Dieter Lentz",

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doi = "10.1021/om2000053",

language = "English",

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AU - Schmiel, Peter

AU - Lentz, Dieter

PY - 2011

Y1 - 2011

N2 - Trifluorovinylcymantrene (1) and -ferrocene (2) form the basis of a versatile building block chemistry. Di- and trinuclear complexes with perfluorinated bridging moieties are obtained by [2+2] cycloaddition on 1 and nucleophilic substitution on the C2F3 unit of 2 with cymantrenyllithium.

AB - Trifluorovinylcymantrene (1) and -ferrocene (2) form the basis of a versatile building block chemistry. Di- and trinuclear complexes with perfluorinated bridging moieties are obtained by [2+2] cycloaddition on 1 and nucleophilic substitution on the C2F3 unit of 2 with cymantrenyllithium.

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U2 - 10.1021/om2000053

DO - 10.1021/om2000053

M3 - Article

AN - SCOPUS:79953693290

SN - 0276-7333

VL - 30

SP - 2063

EP - 2066

JO - Organometallics

JF - Organometallics

IS - 7

ER -

Cymantrene- and ferrocene-based complexes with perfluorinated bridging moieties

Abstract

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