TY - JOUR
T1 - Dalton communications. Rapid characterisation of rhodium dihydrides by nuclear magnetic resonance spectroscopy using indirect two-dimensional methods and para-hydrogen
AU - Duckett, Simon B.
AU - Barlow, Graham K.
AU - Partridge, Martin G.
AU - Messerle, Barbara A.
PY - 1995
Y1 - 1995
N2 - When [RhH2(PMe3)3Cl], incorporating chemically inequivalent hydrides, and [RhH2(PMe3)4]Cl, containing magnetically inequivalent hydrides, were generated using para-enriched hydrogen, their 1H-103Rh and 1H-31P two-dimensional NMR spectra were quickly obtained from < 1 mg of complex with and without the aid of pulsed field gradients.
AB - When [RhH2(PMe3)3Cl], incorporating chemically inequivalent hydrides, and [RhH2(PMe3)4]Cl, containing magnetically inequivalent hydrides, were generated using para-enriched hydrogen, their 1H-103Rh and 1H-31P two-dimensional NMR spectra were quickly obtained from < 1 mg of complex with and without the aid of pulsed field gradients.
UR - http://www.scopus.com/inward/record.url?scp=37049079221&partnerID=8YFLogxK
U2 - 10.1039/DT9950003427
DO - 10.1039/DT9950003427
M3 - Article
AN - SCOPUS:37049079221
SN - 1472-7773
SP - 3427
EP - 3429
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
IS - 20
ER -