Dalton communications. Rapid characterisation of rhodium dihydrides by nuclear magnetic resonance spectroscopy using indirect two-dimensional methods and para-hydrogen

Simon B. Duckett*, Graham K. Barlow, Martin G. Partridge, Barbara A. Messerle

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

36 Citations (Scopus)

Abstract

When [RhH2(PMe3)3Cl], incorporating chemically inequivalent hydrides, and [RhH2(PMe3)4]Cl, containing magnetically inequivalent hydrides, were generated using para-enriched hydrogen, their 1H-103Rh and 1H-31P two-dimensional NMR spectra were quickly obtained from < 1 mg of complex with and without the aid of pulsed field gradients.

Original languageEnglish
Pages (from-to)3427-3429
Number of pages3
JournalJournal of the Chemical Society. Dalton Transactions
Issue number20
DOIs
Publication statusPublished - 1995
Externally publishedYes

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