Design and synthesis of boron complexes as new Raman reporter molecules for sensitive SERS nanotags

Rashid Javaid; Nima Sayyadi; Kausala Mylvaganam; Koushik Venkatesan; Yuling Wang; Alison Rodger

doi:10.1002/jrs.6020

Design and synthesis of boron complexes as new Raman reporter molecules for sensitive SERS nanotags

Rashid Javaid, Nima Sayyadi, Kausala Mylvaganam, Koushik Venkatesan, Yuling Wang, Alison Rodger^*

^*Corresponding author for this work

ARC Centre of Excellence for Nanoscale BioPhotonics (CNBP)

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A new series of boron complexes consisting of pyridine‐pyrazole ligands has been designed, synthesized and evaluated for its Raman activity using solid‐state Raman spectroscopy. The detailed surface‐enhanced Raman scattering (SERS) study of selected dye 2‐(3‐(pyridin‐4‐yl)‐1H‐pyrazol‐5‐yl) pyridine (P₄) on gold nanoparticles (AuNPs) of size 40 nm revealed that it can detect as small as the nanomole level with signal quality that is superior to structurally similar commercially available reporter molecules (RMs), rendering it a suitable RM for sensitive SERS nanotags.

Original language	English
Pages (from-to)	2408-2415
Number of pages	8
Journal	Journal of Raman Spectroscopy
Volume	51
Issue number	12
Early online date	13 Nov 2020
DOIs	https://doi.org/10.1002/jrs.6020
Publication status	Published - Dec 2020

Keywords

boron complexes
molecular design
Raman reporter
pyridine
SERS

Access to Document

10.1002/jrs.6020

Cite this

@article{1f5464f5467145169ed298081179dde5,

title = "Design and synthesis of boron complexes as new Raman reporter molecules for sensitive SERS nanotags",

abstract = "A new series of boron complexes consisting of pyridine‐pyrazole ligands has been designed, synthesized and evaluated for its Raman activity using solid‐state Raman spectroscopy. The detailed surface‐enhanced Raman scattering (SERS) study of selected dye 2‐(3‐(pyridin‐4‐yl)‐1H‐pyrazol‐5‐yl) pyridine (P4) on gold nanoparticles (AuNPs) of size 40 nm revealed that it can detect as small as the nanomole level with signal quality that is superior to structurally similar commercially available reporter molecules (RMs), rendering it a suitable RM for sensitive SERS nanotags.",

keywords = "boron complexes, molecular design, Raman reporter, pyridine, SERS",

author = "Rashid Javaid and Nima Sayyadi and Kausala Mylvaganam and Koushik Venkatesan and Yuling Wang and Alison Rodger",

year = "2020",

month = dec,

doi = "10.1002/jrs.6020",

language = "English",

volume = "51",

pages = "2408--2415",

journal = "Journal of Raman Spectroscopy",

issn = "0377-0486",

publisher = "John Wiley & Sons",

number = "12",

}

TY - JOUR

T1 - Design and synthesis of boron complexes as new Raman reporter molecules for sensitive SERS nanotags

AU - Javaid, Rashid

AU - Sayyadi, Nima

AU - Mylvaganam, Kausala

AU - Venkatesan, Koushik

AU - Wang, Yuling

AU - Rodger, Alison

PY - 2020/12

Y1 - 2020/12

N2 - A new series of boron complexes consisting of pyridine‐pyrazole ligands has been designed, synthesized and evaluated for its Raman activity using solid‐state Raman spectroscopy. The detailed surface‐enhanced Raman scattering (SERS) study of selected dye 2‐(3‐(pyridin‐4‐yl)‐1H‐pyrazol‐5‐yl) pyridine (P4) on gold nanoparticles (AuNPs) of size 40 nm revealed that it can detect as small as the nanomole level with signal quality that is superior to structurally similar commercially available reporter molecules (RMs), rendering it a suitable RM for sensitive SERS nanotags.

AB - A new series of boron complexes consisting of pyridine‐pyrazole ligands has been designed, synthesized and evaluated for its Raman activity using solid‐state Raman spectroscopy. The detailed surface‐enhanced Raman scattering (SERS) study of selected dye 2‐(3‐(pyridin‐4‐yl)‐1H‐pyrazol‐5‐yl) pyridine (P4) on gold nanoparticles (AuNPs) of size 40 nm revealed that it can detect as small as the nanomole level with signal quality that is superior to structurally similar commercially available reporter molecules (RMs), rendering it a suitable RM for sensitive SERS nanotags.

KW - boron complexes

KW - molecular design

KW - Raman reporter

KW - pyridine

KW - SERS

UR - http://www.scopus.com/inward/record.url?scp=85096676373&partnerID=8YFLogxK

U2 - 10.1002/jrs.6020

DO - 10.1002/jrs.6020

M3 - Article

SN - 0377-0486

VL - 51

SP - 2408

EP - 2415

JO - Journal of Raman Spectroscopy

JF - Journal of Raman Spectroscopy

IS - 12

ER -

Design and synthesis of boron complexes as new Raman reporter molecules for sensitive SERS nanotags

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this