Design of ionic liquid 3-methyl-1-sulfonic acid imidazolium nitrate as reagent for the nitration of aromatic compounds by in situ generation of NO 2 in acidic media

Mohammad A. Zolfigol; Ardeshir Khazaei; Ahmad R. Moosavi-Zare; Abdolkarim Zare; Hendrik G. Kruger; Zhila Asgari; Vahid Khakyzadeh; Masoud Kazem-Rostami

doi:10.1021/jo300137w

Design of ionic liquid 3-methyl-1-sulfonic acid imidazolium nitrate as reagent for the nitration of aromatic compounds by in situ generation of NO ₂ in acidic media

Mohammad A. Zolfigol^*, Ardeshir Khazaei, Ahmad R. Moosavi-Zare, Abdolkarim Zare, Hendrik G. Kruger, Zhila Asgari, Vahid Khakyzadeh, Masoud Kazem-Rostami

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

142 Citations (Scopus)

Abstract

3-Methyl-1-sulfonic acid imidazolium nitrate ([Msim]NO ₃) as a new Brønsted acidic ionic liquid and nitrating agent was prepared and used for the efficient nitration of aromatic compounds (even aniline derivatives). The dramatic effect of this reagent by in situ generation of nitrogen dioxide as a radical on aromatic compounds to give nitroarenes has been studied.

Original language	English
Pages (from-to)	3640-3645
Number of pages	6
Journal	Journal of Organic Chemistry
Volume	77
Issue number	7
DOIs	https://doi.org/10.1021/jo300137w
Publication status	Published - 6 Apr 2012
Externally published	Yes

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Zolfigol, M. A., Khazaei, A., Moosavi-Zare, A. R., Zare, A., Kruger, H. G., Asgari, Z., Khakyzadeh, V., & Kazem-Rostami, M. (2012). Design of ionic liquid 3-methyl-1-sulfonic acid imidazolium nitrate as reagent for the nitration of aromatic compounds by in situ generation of NO ₂ in acidic media. Journal of Organic Chemistry, 77(7), 3640-3645. https://doi.org/10.1021/jo300137w

@article{2064d073ac7d4c999a89ec178b377f49,

title = "Design of ionic liquid 3-methyl-1-sulfonic acid imidazolium nitrate as reagent for the nitration of aromatic compounds by in situ generation of NO 2 in acidic media",

abstract = "3-Methyl-1-sulfonic acid imidazolium nitrate ([Msim]NO 3) as a new Br{\o}nsted acidic ionic liquid and nitrating agent was prepared and used for the efficient nitration of aromatic compounds (even aniline derivatives). The dramatic effect of this reagent by in situ generation of nitrogen dioxide as a radical on aromatic compounds to give nitroarenes has been studied.",

author = "Zolfigol, {Mohammad A.} and Ardeshir Khazaei and Moosavi-Zare, {Ahmad R.} and Abdolkarim Zare and Kruger, {Hendrik G.} and Zhila Asgari and Vahid Khakyzadeh and Masoud Kazem-Rostami",

year = "2012",

month = apr,

day = "6",

doi = "10.1021/jo300137w",

language = "English",

volume = "77",

pages = "3640--3645",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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Zolfigol, MA, Khazaei, A, Moosavi-Zare, AR, Zare, A, Kruger, HG, Asgari, Z, Khakyzadeh, V & Kazem-Rostami, M 2012, 'Design of ionic liquid 3-methyl-1-sulfonic acid imidazolium nitrate as reagent for the nitration of aromatic compounds by in situ generation of NO ₂ in acidic media', Journal of Organic Chemistry, vol. 77, no. 7, pp. 3640-3645. https://doi.org/10.1021/jo300137w

Design of ionic liquid 3-methyl-1-sulfonic acid imidazolium nitrate as reagent for the nitration of aromatic compounds by in situ generation of NO ₂ in acidic media. / Zolfigol, Mohammad A.; Khazaei, Ardeshir; Moosavi-Zare, Ahmad R. et al.

In: Journal of Organic Chemistry, Vol. 77, No. 7, 06.04.2012, p. 3640-3645.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Design of ionic liquid 3-methyl-1-sulfonic acid imidazolium nitrate as reagent for the nitration of aromatic compounds by in situ generation of NO 2 in acidic media

AU - Zolfigol, Mohammad A.

AU - Khazaei, Ardeshir

AU - Moosavi-Zare, Ahmad R.

AU - Zare, Abdolkarim

AU - Kruger, Hendrik G.

AU - Asgari, Zhila

AU - Khakyzadeh, Vahid

AU - Kazem-Rostami, Masoud

PY - 2012/4/6

Y1 - 2012/4/6

N2 - 3-Methyl-1-sulfonic acid imidazolium nitrate ([Msim]NO 3) as a new Brønsted acidic ionic liquid and nitrating agent was prepared and used for the efficient nitration of aromatic compounds (even aniline derivatives). The dramatic effect of this reagent by in situ generation of nitrogen dioxide as a radical on aromatic compounds to give nitroarenes has been studied.

AB - 3-Methyl-1-sulfonic acid imidazolium nitrate ([Msim]NO 3) as a new Brønsted acidic ionic liquid and nitrating agent was prepared and used for the efficient nitration of aromatic compounds (even aniline derivatives). The dramatic effect of this reagent by in situ generation of nitrogen dioxide as a radical on aromatic compounds to give nitroarenes has been studied.

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SP - 3640

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JF - Journal of Organic Chemistry

SN - 0022-3263

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Design of ionic liquid 3-methyl-1-sulfonic acid imidazolium nitrate as reagent for the nitration of aromatic compounds by in situ generation of NO ₂ in acidic media

Abstract

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