Determination of the longer chain n-alkyl content of coals

Matilda Kolandaisamy*, Barry D. Batts, John W. Smith

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Yields of longer chain n-alkanes, consistently higher than those resulting from hydrous pyrolysis, are obtained when coals are hydrogenated using a sulphided nickel-molybdenum catalyst rather than a copper chromite catalyst. The lower yields of n-alkanes are attributed to: the incomplete conversion of carboxylic acids together with thermal chain splitting reactions under hydrous pyrolysis conditions; and deterioration in the activity of the copper chromite catalyst used in hydrogenation. A sequential hydrous pyrolysis/hydrogenation procedure failed to demonstrate that the physical release of n-alkanes from coal is significantly favoured by hydrous pyrolysis. Therefore, hydrogenation in the presence of a sulphided catalyst is superior to hydrous pyrolysis in the determination of n-alkyl content of coals.

Original languageEnglish
Pages (from-to)1322-1325
Number of pages4
JournalFuel
Volume69
Issue number10
DOIs
Publication statusPublished - 1990

Keywords

  • coal
  • hydrogenation
  • n-alkyl yield

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