Diamonds are a spectroscopists best friend

Thin-film diamond mid-infrared waveguides for advanced chemical sensors/biosensors

Xiaofeng Wang, Mikael Karlsson, Pontus Forsberg, Markus Sieger, Fredrik Nikolajeff, Lars Österlund*, Boris Mizaikoff

*Corresponding author for this work

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The first combination of mid-infrared (MIR) tunable quantum cascade lasers (tQCLs) with thin-film diamond strip waveguides (DSWGs) suitable for advanced chemical sensing/biosensing is demonstrated. The sensing system is composed of thin diamond films grown on surface-passivated Si wafers via chemical vapor deposition (CVD) and microstructured using inductively coupled plasma (ICP) etching, serving as photonic waveguides for radiation emitted by a broadly tunable quantum cascade laser (tQCL) in the spectral regime of 5.78-6.35 μm (1570-1730 cm-1). The characterization of the free-standing diamond waveguides reveals excellent transmission properties across a broad MIR band. As a proof of concept, the detection of acetone in D2O via evanescent field absorption is demonstrated achieving a limit of detection (LOD) as low as 200 pL, which indicates a significant sensitivity improvement compared to conventional MIR slab/strip waveguides reported to date. Providing characteristic absorption features within the tuning range of the tQCL, studies using anisaldehyde as an analyte further corroborate the potential of tQCL-DSWG-based chemical sensors/biosensors.

Original languageEnglish
Pages (from-to)8136-8141
Number of pages6
JournalAnalytical Chemistry
Volume86
Issue number16
DOIs
Publication statusPublished - 19 Aug 2014
Externally publishedYes

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    Wang, X., Karlsson, M., Forsberg, P., Sieger, M., Nikolajeff, F., Österlund, L., & Mizaikoff, B. (2014). Diamonds are a spectroscopists best friend: Thin-film diamond mid-infrared waveguides for advanced chemical sensors/biosensors. Analytical Chemistry, 86(16), 8136-8141. https://doi.org/10.1021/ac5011475