Dielectric saturation and dielectric friction in electrolyte solutions

P. J. Stiles*, J. B. Hubbard, R. F. Kayser

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    35 Citations (Scopus)

    Abstract

    Electrohydrodynamic equations developed by Hubbard and Kayser to account for the combined effects of dielectric saturation and dielectric friction on ionic motion in polar solvents are solved numerically to yield ionic conductances. Dielectric saturation is incorporated into this continuum treatment through a phenomenological relationship between the electric permittivity and field strength. The results of the analysis are critically tested by comparison with experimental conductance data.

    Original languageEnglish
    Pages (from-to)6189-6196
    Number of pages8
    JournalThe Journal of Chemical Physics
    Volume77
    Publication statusPublished - 1982

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