Dielectric saturation and dielectric friction in electrolyte solutions

P. J. Stiles*, J. B. Hubbard, R. F. Kayser

*Corresponding author for this work

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Electrohydrodynamic equations developed by Hubbard and Kayser to account for the combined effects of dielectric saturation and dielectric friction on ionic motion in polar solvents are solved numerically to yield ionic conductances. Dielectric saturation is incorporated into this continuum treatment through a phenomenological relationship between the electric permittivity and field strength. The results of the analysis are critically tested by comparison with experimental conductance data.

Original languageEnglish
Pages (from-to)6189-6196
Number of pages8
JournalThe Journal of Chemical Physics
Volume77
Publication statusPublished - 1982

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    Stiles, P. J., Hubbard, J. B., & Kayser, R. F. (1982). Dielectric saturation and dielectric friction in electrolyte solutions. The Journal of Chemical Physics, 77, 6189-6196.