Diethyl 4,10-dibromo-5,11 -methano-6H, 12H-dibenzo [b,f] [1,5]diazocine-2,8-dicarboxylate

M. Delower H Bhuiyan; Andrew C. Try; John Klepetko; Peter Turner

doi:10.1107/S1600536806040505

Diethyl 4,10-dibromo-5,11 -methano-6H, 12H-dibenzo [b,f] [1,5]diazocine-2,8-dicarboxylate

M. Delower H Bhuiyan, Andrew C. Try^*, John Klepetko, Peter Turner

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

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Abstract

In the molecule of the title compound, C₂₁H₂₀Br ₂N₂O₄, the 4,10-dibromo-2,8-diethyl ester analogue of Tröger's base, the diazocine bridge imparts a twist such that the two aryl rings are offset with respect to one another. A twofold rotation axis passes through the bridgehead C atom. The asymmetric unit contains only one-half molecule and the dihedral angle between the two symmetry-related benzene rings is 98.24 (4)°.

Original language	English
Pages (from-to)	o4887-o4888
Number of pages	2
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	11
DOIs	https://doi.org/10.1107/S1600536806040505
Publication status	Published - Nov 2006

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title = "Diethyl 4,10-dibromo-5,11 -methano-6H, 12H-dibenzo [b,f] [1,5]diazocine-2,8-dicarboxylate",

abstract = "In the molecule of the title compound, C21H20Br 2N2O4, the 4,10-dibromo-2,8-diethyl ester analogue of Tr{\"o}ger's base, the diazocine bridge imparts a twist such that the two aryl rings are offset with respect to one another. A twofold rotation axis passes through the bridgehead C atom. The asymmetric unit contains only one-half molecule and the dihedral angle between the two symmetry-related benzene rings is 98.24 (4)°.",

author = "Bhuiyan, \{M. Delower H\} and Try, \{Andrew C.\} and John Klepetko and Peter Turner",

year = "2006",

month = nov,

doi = "10.1107/S1600536806040505",

language = "English",

volume = "62",

pages = "o4887--o4888",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "11",

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T1 - Diethyl 4,10-dibromo-5,11 -methano-6H, 12H-dibenzo [b,f] [1,5]diazocine-2,8-dicarboxylate

AU - Bhuiyan, M. Delower H

AU - Try, Andrew C.

AU - Klepetko, John

AU - Turner, Peter

PY - 2006/11

Y1 - 2006/11

N2 - In the molecule of the title compound, C21H20Br 2N2O4, the 4,10-dibromo-2,8-diethyl ester analogue of Tröger's base, the diazocine bridge imparts a twist such that the two aryl rings are offset with respect to one another. A twofold rotation axis passes through the bridgehead C atom. The asymmetric unit contains only one-half molecule and the dihedral angle between the two symmetry-related benzene rings is 98.24 (4)°.

AB - In the molecule of the title compound, C21H20Br 2N2O4, the 4,10-dibromo-2,8-diethyl ester analogue of Tröger's base, the diazocine bridge imparts a twist such that the two aryl rings are offset with respect to one another. A twofold rotation axis passes through the bridgehead C atom. The asymmetric unit contains only one-half molecule and the dihedral angle between the two symmetry-related benzene rings is 98.24 (4)°.

UR - https://www.scopus.com/pages/publications/33750860727

U2 - 10.1107/S1600536806040505

DO - 10.1107/S1600536806040505

M3 - Article

AN - SCOPUS:33750860727

SN - 1600-5368

VL - 62

SP - o4887-o4888

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Diethyl 4,10-dibromo-5,11 -methano-6H, 12H-dibenzo [b,f] [1,5]diazocine-2,8-dicarboxylate

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