Dipole moments of diatomic molecules

B. F. Gray*, H. O. Pritchard

*Corresponding author for this work

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Abstract

The effect of the presence of an electric field on the adiabatic approximation for a diatomic molecule is considered, and it is concluded that, to within experimental accuracy, the dipole moment can be calculated by averaging the "static" dipole moment over the molecular vibration. The variation of molecular dipole with vibrational excitation is investigated numerically, and, in an appendix, a possible inversion in relative vibrational absorption intensities is predicted.

Original languageEnglish
Pages (from-to)137-143
Number of pages7
JournalJournal of Molecular Spectroscopy
Volume2
Issue number1-6
Publication statusPublished - 1958
Externally publishedYes

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Gray, B. F., & Pritchard, H. O. (1958). Dipole moments of diatomic molecules. Journal of Molecular Spectroscopy, 2(1-6), 137-143.