Dynamic percolation theory for particle diffusion in a polymer network

O. Dürr*, T. Volz, W. Dieterich, A. Nitzan

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

20 Citations (Scopus)

Abstract

The tracer-diffusion of small molecules through dense system of chain polymers within an athermal lattice model was discussed. An approximate mapping of this problem based on dynamic percolation theory (DPT) was proposed. The analysis showed that the proposed method yielded quantitative results for the tracer correlation factor of the molecules as a function of density and chain length, provided the non-Poisson character of the temporal renewals in the disorder configurations was properly taken into account.

Original languageEnglish
Pages (from-to)441-447
Number of pages7
JournalJournal of Chemical Physics
Volume117
Issue number1
DOIs
Publication statusPublished - 1 Jul 2002
Externally publishedYes

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