Efficient light harvesting in hybrid quantum dot-interdigitated back contact solar cells via resonant energy transfer and luminescent downshifting

Chirenjeevi Krishnan*, Thomas Mercier, Tasmiat Rahman, Giacomo Piana, Mael Brossard, Timur Yagafarov, Alexander To, Michael E. Pollard, Peter Shaw, Darren M. Bagnall, Bram Hoex, Stuart A. Boden, Pavlos G. Lagoudakis, Martin D. B. Charlton

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)
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Abstract

In this paper, we propose a hybrid quantum dot (QD)/solar cell configuration to improve performance of interdigitated back contact (IBC) silicon solar cells, resulting in 39.5% relative boost in the short-circuit current (JSC) through efficient utilisation of resonant energy transfer (RET) and luminescent downshifting (LDS). A uniform layer of CdSe1-xSx/ZnS quantum dots is deposited onto the AlOx surface passivation layer of the IBC solar cell. QD hybridization is found to cause a broadband improvement in the solar cell external quantum efficiency. Enhancement over the QD absorption wavelength range is shown to result from LDS. This is confirmed by significant boosts in the solar cell internal quantum efficiency (IQE) due to the presence of QDs. Enhancement over the red and near-infrared spectral range is shown to result from the anti-reflection properties of the QD layer coating. A study on the effect of QD layer thickness on solar cell performance was performed and an optimised QD layer thickness was determined. Time-resolved photoluminescence (TRPL) spectroscopy was used to investigate the photoluminescence dynamics of the QD layer as a function of AlOx spacer layer thickness. RET can be evoked between the QD and Si layers for very thin AlOx spacer layers, with RET efficiencies of up to 15%. In the conventional LDS architecture, down-converters are deposited on the surface of an optimised anti-reflection layer, providing relatively narrowband enhancement, whereas the QDs in our hybrid architecture provide optical enhancement over the broadband wavelength range, by simultaneously utilising LDS, RET-mediated carrier injection, and antireflection effects, resulting in up to 40% improvement in the power conversion efficiency (PCE). Low-cost synthesis of QDs and simple device integration provide a cost-effective solution for boosting solar cell performance.

Original languageEnglish
Pages (from-to)18837-18844
Number of pages8
JournalNanoscale
Volume11
Issue number40
DOIs
Publication statusPublished - 28 Oct 2019

Bibliographical note

Copyright the Publisher 2019. Version archived for private and non-commercial use with the permission of the author/s and according to publisher conditions. For further rights please contact the publisher.

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