Electrochemical behavior of anatase TiO 2 in aqueous lithium hydroxide electrolyte

Minakshi Manickam; Pritam Singh; Touma B. Issa; Stephen Thurgate

doi:10.1007/s10800-005-9112-9

Electrochemical behavior of anatase TiO 2 in aqueous lithium hydroxide electrolyte

Minakshi Manickam^*, Pritam Singh, Touma B. Issa, Stephen Thurgate

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

The electrochemical behavior of titanium dioxide (TiO ₂) in aqueous lithium hydroxide (LiOH) electrolyte has been investigated. Cyclic voltammetry shows that electroreduction results in the formation of a number of products. X-ray diffraction of the electroreduced TiO ₂ shows that Li _xTiO ₂, Ti ₂O ₃, Ti ₂O and TiO are formed. The formation of Li _xTiO ₂ is confirmed through X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) studies of the electroreduced TiO ₂. The formation of Li _xTiO ₂ is electro reversible. In this respect, the electrochemical behavior of TiO ₂ in concentrated aqueous lithium hydroxide electrolyte is similar to that for lithium perchlorate (LiClO ₄) non-aqueous media.

Original language	English
Pages (from-to)	599-602
Number of pages	4
Journal	Journal of Applied Electrochemistry
Volume	36
Issue number	5
DOIs	https://doi.org/10.1007/s10800-005-9112-9
Publication status	Published - May 2006

Keywords

Anatase
LiTiO
Oxidation
Reduction
TiO

Access to Document

10.1007/s10800-005-9112-9

Cite this

@article{956d9be95bf04ea584048d485268486f,

title = "Electrochemical behavior of anatase TiO 2 in aqueous lithium hydroxide electrolyte",

abstract = "The electrochemical behavior of titanium dioxide (TiO 2) in aqueous lithium hydroxide (LiOH) electrolyte has been investigated. Cyclic voltammetry shows that electroreduction results in the formation of a number of products. X-ray diffraction of the electroreduced TiO 2 shows that Li xTiO 2, Ti 2O 3, Ti 2O and TiO are formed. The formation of Li xTiO 2 is confirmed through X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) studies of the electroreduced TiO 2. The formation of Li xTiO 2 is electro reversible. In this respect, the electrochemical behavior of TiO 2 in concentrated aqueous lithium hydroxide electrolyte is similar to that for lithium perchlorate (LiClO 4) non-aqueous media.",

keywords = "Anatase, LiTiO, Oxidation, Reduction, TiO",

author = "Minakshi Manickam and Pritam Singh and Issa, {Touma B.} and Stephen Thurgate",

year = "2006",

month = may,

doi = "10.1007/s10800-005-9112-9",

language = "English",

volume = "36",

pages = "599--602",

journal = "Journal of Applied Electrochemistry",

issn = "0021-891X",

publisher = "Springer, Springer Nature",

number = "5",

}

TY - JOUR

T1 - Electrochemical behavior of anatase TiO 2 in aqueous lithium hydroxide electrolyte

AU - Manickam, Minakshi

AU - Singh, Pritam

AU - Issa, Touma B.

AU - Thurgate, Stephen

PY - 2006/5

Y1 - 2006/5

N2 - The electrochemical behavior of titanium dioxide (TiO 2) in aqueous lithium hydroxide (LiOH) electrolyte has been investigated. Cyclic voltammetry shows that electroreduction results in the formation of a number of products. X-ray diffraction of the electroreduced TiO 2 shows that Li xTiO 2, Ti 2O 3, Ti 2O and TiO are formed. The formation of Li xTiO 2 is confirmed through X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) studies of the electroreduced TiO 2. The formation of Li xTiO 2 is electro reversible. In this respect, the electrochemical behavior of TiO 2 in concentrated aqueous lithium hydroxide electrolyte is similar to that for lithium perchlorate (LiClO 4) non-aqueous media.

AB - The electrochemical behavior of titanium dioxide (TiO 2) in aqueous lithium hydroxide (LiOH) electrolyte has been investigated. Cyclic voltammetry shows that electroreduction results in the formation of a number of products. X-ray diffraction of the electroreduced TiO 2 shows that Li xTiO 2, Ti 2O 3, Ti 2O and TiO are formed. The formation of Li xTiO 2 is confirmed through X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) studies of the electroreduced TiO 2. The formation of Li xTiO 2 is electro reversible. In this respect, the electrochemical behavior of TiO 2 in concentrated aqueous lithium hydroxide electrolyte is similar to that for lithium perchlorate (LiClO 4) non-aqueous media.

KW - Anatase

KW - LiTiO

KW - Oxidation

KW - Reduction

KW - TiO

UR - http://www.scopus.com/inward/record.url?scp=33646386429&partnerID=8YFLogxK

U2 - 10.1007/s10800-005-9112-9

DO - 10.1007/s10800-005-9112-9

M3 - Article

AN - SCOPUS:33646386429

SN - 0021-891X

VL - 36

SP - 599

EP - 602

JO - Journal of Applied Electrochemistry

JF - Journal of Applied Electrochemistry

IS - 5

ER -

Electrochemical behavior of anatase TiO 2 in aqueous lithium hydroxide electrolyte

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this