Electrochemical behavior of olivine-type LiMnPO 4 in aqueous solutions

Manickam Minakshi; Pritam Singh; Stephen Thurgate; Kathryn Prince

doi:10.1149/1.2236379

Electrochemical behavior of olivine-type LiMnPO 4 in aqueous solutions

Manickam Minakshi^*, Pritam Singh, Stephen Thurgate, Kathryn Prince

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

The electrochemical behavior of olivine-type lithium manganese phosphate (LiMnPO ₄) as a cathode material was investigated in a saturated aqueous lithium hydroxide electrolyte. The crystal structure and surface characterization of the olivine type LiMnPO ₄ and the products which are formed on its oxidation and subsequent reduction were studied. X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, and secondary ion mass spectrometry were used for these investigations. LiMnPO ₄ was found to be reversibly delithiated/lithiated on electro-oxidation/reduction.

Original language	English
Journal	Electrochemical and Solid-State Letters
Volume	9
Issue number	10
DOIs	https://doi.org/10.1149/1.2236379
Publication status	Published - 2006

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abstract = "The electrochemical behavior of olivine-type lithium manganese phosphate (LiMnPO 4) as a cathode material was investigated in a saturated aqueous lithium hydroxide electrolyte. The crystal structure and surface characterization of the olivine type LiMnPO 4 and the products which are formed on its oxidation and subsequent reduction were studied. X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, and secondary ion mass spectrometry were used for these investigations. LiMnPO 4 was found to be reversibly delithiated/lithiated on electro-oxidation/reduction.",

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AU - Minakshi, Manickam

AU - Singh, Pritam

AU - Thurgate, Stephen

AU - Prince, Kathryn

PY - 2006

Y1 - 2006

N2 - The electrochemical behavior of olivine-type lithium manganese phosphate (LiMnPO 4) as a cathode material was investigated in a saturated aqueous lithium hydroxide electrolyte. The crystal structure and surface characterization of the olivine type LiMnPO 4 and the products which are formed on its oxidation and subsequent reduction were studied. X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, and secondary ion mass spectrometry were used for these investigations. LiMnPO 4 was found to be reversibly delithiated/lithiated on electro-oxidation/reduction.

AB - The electrochemical behavior of olivine-type lithium manganese phosphate (LiMnPO 4) as a cathode material was investigated in a saturated aqueous lithium hydroxide electrolyte. The crystal structure and surface characterization of the olivine type LiMnPO 4 and the products which are formed on its oxidation and subsequent reduction were studied. X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, and secondary ion mass spectrometry were used for these investigations. LiMnPO 4 was found to be reversibly delithiated/lithiated on electro-oxidation/reduction.

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JO - Electrochemical and Solid-State Letters

JF - Electrochemical and Solid-State Letters

SN - 1099-0062

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ER -

Electrochemical behavior of olivine-type LiMnPO 4 in aqueous solutions

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