Electron spin resonance studies of the mechanism of interaction between nitrogen dioxide and olefinic solvents

B. H J Bielski; J. M. Gebicki

Electron spin resonance studies of the mechanism of interaction between nitrogen dioxide and olefinic solvents

B. H J Bielski^*, J. M. Gebicki

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The electron spin resonance spectra of nitrogen dioxide dissolved in several unsaturated solvents consisted of triplets with an average ¹⁴N splitting of about 13 G. Two triplets of equal intensity were recorded in solvents which had aromatic as well as olefinic character, the splitting of the triplet being due to interaction with a single solvent proton. The results were interpreted in terms of formation of an NO₂-olefin π complex in an exothermic process. This precedes the well-known reaction which leads to nitration of the olefin.

Original language	English
Pages (from-to)	1402-1406
Number of pages	5
Journal	Journal of Physical Chemistry
Volume	73
Issue number	5
Publication status	Published - 1969
Externally published	Yes

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title = "Electron spin resonance studies of the mechanism of interaction between nitrogen dioxide and olefinic solvents",

abstract = "The electron spin resonance spectra of nitrogen dioxide dissolved in several unsaturated solvents consisted of triplets with an average 14N splitting of about 13 G. Two triplets of equal intensity were recorded in solvents which had aromatic as well as olefinic character, the splitting of the triplet being due to interaction with a single solvent proton. The results were interpreted in terms of formation of an NO2-olefin π complex in an exothermic process. This precedes the well-known reaction which leads to nitration of the olefin.",

author = "Bielski, {B. H J} and Gebicki, {J. M.}",

year = "1969",

language = "English",

volume = "73",

pages = "1402--1406",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - Electron spin resonance studies of the mechanism of interaction between nitrogen dioxide and olefinic solvents

AU - Bielski, B. H J

AU - Gebicki, J. M.

PY - 1969

Y1 - 1969

N2 - The electron spin resonance spectra of nitrogen dioxide dissolved in several unsaturated solvents consisted of triplets with an average 14N splitting of about 13 G. Two triplets of equal intensity were recorded in solvents which had aromatic as well as olefinic character, the splitting of the triplet being due to interaction with a single solvent proton. The results were interpreted in terms of formation of an NO2-olefin π complex in an exothermic process. This precedes the well-known reaction which leads to nitration of the olefin.

AB - The electron spin resonance spectra of nitrogen dioxide dissolved in several unsaturated solvents consisted of triplets with an average 14N splitting of about 13 G. Two triplets of equal intensity were recorded in solvents which had aromatic as well as olefinic character, the splitting of the triplet being due to interaction with a single solvent proton. The results were interpreted in terms of formation of an NO2-olefin π complex in an exothermic process. This precedes the well-known reaction which leads to nitration of the olefin.

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M3 - Article

AN - SCOPUS:3843053498

VL - 73

SP - 1402

EP - 1406

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

SN - 0022-3654

IS - 5

ER -