Electronic excitations in vanadium oxide phthalocyanine studied via resonant soft X-ray emission and resonant inelastic X-ray scattering

Yufeng Zhang; Shancai Wang; Timothy Learmonth; Lukasz Plucinski; A. Y. Matsuura; Sarah Bernardis; Cian O'Donnell; James E. Downes; Kevin E. Smith

doi:10.1016/j.cplett.2005.07.066

Electronic excitations in vanadium oxide phthalocyanine studied via resonant soft X-ray emission and resonant inelastic X-ray scattering

Yufeng Zhang, Shancai Wang, Timothy Learmonth, Lukasz Plucinski, A. Y. Matsuura, Sarah Bernardis, Cian O'Donnell, James E. Downes, Kevin E. Smith^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The electronic structure of the organic semiconductor vanadium oxide phthalocyanine has been studied using resonant inelastic X-ray scattering and X-ray emission spectroscopy. The vanadyl species in the films is shown to be highly localized, and good agreement between the measurements and a density functional calculation is obtained. Both dipole forbidden V 3d to V 3d*, and O 2p to V 3d* charge transfer transitions are observed, and explained in a local molecular orbital model.

Original language	English
Pages (from-to)	95-99
Number of pages	5
Journal	Chemical Physics Letters
Volume	413
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2005.07.066
Publication status	Published - 15 Sept 2005
Externally published	Yes

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10.1016/j.cplett.2005.07.066

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title = "Electronic excitations in vanadium oxide phthalocyanine studied via resonant soft X-ray emission and resonant inelastic X-ray scattering",

abstract = "The electronic structure of the organic semiconductor vanadium oxide phthalocyanine has been studied using resonant inelastic X-ray scattering and X-ray emission spectroscopy. The vanadyl species in the films is shown to be highly localized, and good agreement between the measurements and a density functional calculation is obtained. Both dipole forbidden V 3d to V 3d*, and O 2p to V 3d* charge transfer transitions are observed, and explained in a local molecular orbital model.",

author = "Yufeng Zhang and Shancai Wang and Timothy Learmonth and Lukasz Plucinski and Matsuura, {A. Y.} and Sarah Bernardis and Cian O'Donnell and Downes, {James E.} and Smith, {Kevin E.}",

year = "2005",

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doi = "10.1016/j.cplett.2005.07.066",

language = "English",

volume = "413",

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journal = "Chemical Physics Letters",

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T1 - Electronic excitations in vanadium oxide phthalocyanine studied via resonant soft X-ray emission and resonant inelastic X-ray scattering

AU - Zhang, Yufeng

AU - Wang, Shancai

AU - Learmonth, Timothy

AU - Plucinski, Lukasz

AU - Matsuura, A. Y.

AU - Bernardis, Sarah

AU - O'Donnell, Cian

AU - Downes, James E.

AU - Smith, Kevin E.

PY - 2005/9/15

Y1 - 2005/9/15

N2 - The electronic structure of the organic semiconductor vanadium oxide phthalocyanine has been studied using resonant inelastic X-ray scattering and X-ray emission spectroscopy. The vanadyl species in the films is shown to be highly localized, and good agreement between the measurements and a density functional calculation is obtained. Both dipole forbidden V 3d to V 3d*, and O 2p to V 3d* charge transfer transitions are observed, and explained in a local molecular orbital model.

AB - The electronic structure of the organic semiconductor vanadium oxide phthalocyanine has been studied using resonant inelastic X-ray scattering and X-ray emission spectroscopy. The vanadyl species in the films is shown to be highly localized, and good agreement between the measurements and a density functional calculation is obtained. Both dipole forbidden V 3d to V 3d*, and O 2p to V 3d* charge transfer transitions are observed, and explained in a local molecular orbital model.

UR - http://www.scopus.com/inward/record.url?scp=24344438872&partnerID=8YFLogxK

U2 - 10.1016/j.cplett.2005.07.066

DO - 10.1016/j.cplett.2005.07.066

M3 - Article

AN - SCOPUS:24344438872

SN - 0009-2614

VL - 413

SP - 95

EP - 99

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-3

ER -

Electronic excitations in vanadium oxide phthalocyanine studied via resonant soft X-ray emission and resonant inelastic X-ray scattering

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