Electrostriction and dielectric friction on ions moving through compressible polar solvents

P. J. Stiles; J. B. Hubbard

doi:10.1016/0009-2614(84)85676-6

Electrostriction and dielectric friction on ions moving through compressible polar solvents

P. J. Stiles^*, J. B. Hubbard

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The Hubbard-Onsager electrohydrodynamic model is extended to examine the influence of electrostriction on the mobilities of large ions in compressible polar solvents. We find that electrostriction leads to significant augmentation of the drag coefficients of large ions in aprotic solvents such as acetonitrile and acetone.

Original language	English
Pages (from-to)	655-658
Number of pages	4
Journal	Chemical Physics Letters
Volume	105
Issue number	6
DOIs	https://doi.org/10.1016/0009-2614(84)85676-6
Publication status	Published - 6 Apr 1984

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title = "Electrostriction and dielectric friction on ions moving through compressible polar solvents",

abstract = "The Hubbard-Onsager electrohydrodynamic model is extended to examine the influence of electrostriction on the mobilities of large ions in compressible polar solvents. We find that electrostriction leads to significant augmentation of the drag coefficients of large ions in aprotic solvents such as acetonitrile and acetone.",

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T1 - Electrostriction and dielectric friction on ions moving through compressible polar solvents

AU - Stiles, P. J.

AU - Hubbard, J. B.

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N2 - The Hubbard-Onsager electrohydrodynamic model is extended to examine the influence of electrostriction on the mobilities of large ions in compressible polar solvents. We find that electrostriction leads to significant augmentation of the drag coefficients of large ions in aprotic solvents such as acetonitrile and acetone.

AB - The Hubbard-Onsager electrohydrodynamic model is extended to examine the influence of electrostriction on the mobilities of large ions in compressible polar solvents. We find that electrostriction leads to significant augmentation of the drag coefficients of large ions in aprotic solvents such as acetonitrile and acetone.

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DO - 10.1016/0009-2614(84)85676-6

M3 - Article

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VL - 105

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EP - 658

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 6

ER -

Electrostriction and dielectric friction on ions moving through compressible polar solvents

Abstract

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