Fluoride-assisted regioselective conversion of functionalized furans to α-substituted γ-hydroxybutenolides using singlet oxygen

Santoshkumar N. Patil; Fei Liu

doi:10.1021/jo070666c

Fluoride-assisted regioselective conversion of functionalized furans to α-substituted γ-hydroxybutenolides using singlet oxygen

Santoshkumar N. Patil, Fei Liu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

(Chemical Equation Presented) A facile synthesis of α-substituted γ-hydroxybutenolides from 3-furfural was achieved using a Baylis-Hillman reaction followed by singlet oxygen oxidation. The regioselectivity of this conversion was controlled by using TBAF.

Original language	English
Pages (from-to)	6305-6308
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	72
Issue number	16
DOIs	https://doi.org/10.1021/jo070666c
Publication status	Published - Aug 2007

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@article{4f87141912ff4b9da1abb70588603ac5,

title = "Fluoride-assisted regioselective conversion of functionalized furans to α-substituted γ-hydroxybutenolides using singlet oxygen",

abstract = "(Chemical Equation Presented) A facile synthesis of α-substituted γ-hydroxybutenolides from 3-furfural was achieved using a Baylis-Hillman reaction followed by singlet oxygen oxidation. The regioselectivity of this conversion was controlled by using TBAF.",

author = "Patil, {Santoshkumar N.} and Fei Liu",

year = "2007",

month = aug,

doi = "10.1021/jo070666c",

language = "English",

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issn = "0022-3263",

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T1 - Fluoride-assisted regioselective conversion of functionalized furans to α-substituted γ-hydroxybutenolides using singlet oxygen

AU - Patil, Santoshkumar N.

AU - Liu, Fei

PY - 2007/8

Y1 - 2007/8

N2 - (Chemical Equation Presented) A facile synthesis of α-substituted γ-hydroxybutenolides from 3-furfural was achieved using a Baylis-Hillman reaction followed by singlet oxygen oxidation. The regioselectivity of this conversion was controlled by using TBAF.

AB - (Chemical Equation Presented) A facile synthesis of α-substituted γ-hydroxybutenolides from 3-furfural was achieved using a Baylis-Hillman reaction followed by singlet oxygen oxidation. The regioselectivity of this conversion was controlled by using TBAF.

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U2 - 10.1021/jo070666c

DO - 10.1021/jo070666c

M3 - Article

C2 - 17629339

AN - SCOPUS:34547644884

SN - 0022-3263

VL - 72

SP - 6305

EP - 6308

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 16

ER -

Fluoride-assisted regioselective conversion of functionalized furans to α-substituted γ-hydroxybutenolides using singlet oxygen

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