TY - JOUR
T1 - Formation of a novel dipyrrolopyrrole mediated by a 1,4-diaza-1,3-diene complex of iron
AU - Buys, Irmi E.
AU - Elgafi, Sarah
AU - Field, Leslie D.
AU - Hambley, Trevor W.
AU - Messerle, Barbara A.
PY - 1994
Y1 - 1994
N2 - The dipyrrolopyrrole 2,6-bis(p-tolylimino)-4,7-dihydro-1,4,7-tri-p-tolyl-1H-dipyrrolo[3,2-b:2′, 3′-d]pyrrole (1) was obtained from the reaction of a 1,4-diaza-1,3-diene, glyoxal bis(p-tolylimine), in the presence of FeCl2. Crystals of 1, C43H32N5, are triclinic, space group, P1, with a = 10.014(3) Å, b = 13.212(3) Å, c = 13.710(3) Å, α = 106.31(2)°, β = 95.79(2)°, γ = 105.77(2)°, V = 1644 Å3 , Z = 2, Dcalcd = 1.211 g cm-1, R = 0.026, and Rw = 0.057. The compound is thought to result from a series of metal-mediated condensations of the 1,4-diaza-1,3-diene precursor.
AB - The dipyrrolopyrrole 2,6-bis(p-tolylimino)-4,7-dihydro-1,4,7-tri-p-tolyl-1H-dipyrrolo[3,2-b:2′, 3′-d]pyrrole (1) was obtained from the reaction of a 1,4-diaza-1,3-diene, glyoxal bis(p-tolylimine), in the presence of FeCl2. Crystals of 1, C43H32N5, are triclinic, space group, P1, with a = 10.014(3) Å, b = 13.212(3) Å, c = 13.710(3) Å, α = 106.31(2)°, β = 95.79(2)°, γ = 105.77(2)°, V = 1644 Å3 , Z = 2, Dcalcd = 1.211 g cm-1, R = 0.026, and Rw = 0.057. The compound is thought to result from a series of metal-mediated condensations of the 1,4-diaza-1,3-diene precursor.
UR - http://www.scopus.com/inward/record.url?scp=33645048853&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:33645048853
SN - 0020-1669
VL - 33
SP - 1539
EP - 1542
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 7
ER -